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Concept explainers
(a)
Interpretation:
The curved arrow mechanism and structure of X for the given reaction of
Concept introduction:
Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.
(b)
Interpretation:
The proximity effect value is to be calculated.
Concept introduction:
Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.
(c)
Interpretation:
The reason as to why the proximity value is smaller than the effect calculated for the similar reaction is to be stated. .
Concept introduction:
Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.
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Chapter 11 Solutions
Organic Chemistry Study Guide and Solutions
- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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