(a) Interpretation: The mechanism and observation for the reaction of compound A to give t r a n s − B compound are to be stated. Concept introduction: Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 1

Question

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 2

Question

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 3

Question

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 4

Question

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

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Answer 5

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 6

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 7

Chapter 11, Problem 11.73AP

Interpretation Introduction

(a)

Interpretation:

The mechanism and observation for the reaction of compound A to give trans−B compound are to be stated.

Concept introduction:

Neighbouring group participation is the interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism and observation for the reaction in which optically active compound A gives racemic B are to be stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the rate of the reaction of A is 105 times faster than compound C and chlorocyclohexane is to stated.

Concept introduction:

Neighbouring group participation isthe interaction of the lone pair electrons of an atom (hetero) or electron present in sigma and pi bond with the parent molecule to increase the speed of the reaction. It is also known as anchimeric assistance.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

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