The detailed mechanism and major product of the given reaction are to be shown. Concept introduction: This is an electrophilic addition reaction via carbocation rearrangement. The electrophilic addition of a Bronsted acid across a carbon-carbon double bond is susceptible to carbocation rearrangement. A carbocation rearrangement transforms the less stable carbocation into a more stable carbocation to attain greater stability via 1, 2 - hydride shift or 1, 2 - methyl shift . Electrophilic addition reaction proceeds through a carbocation intermediate.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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Question

Chapter 11, Problem 11.6P

Interpretation Introduction

Interpretation:

The detailed mechanism and major product of the given reaction are to be shown.

Concept introduction:

This is an electrophilic addition reaction via carbocation rearrangement. The electrophilic addition of a Bronsted acid across a carbon-carbon double bond is susceptible to carbocation rearrangement. A carbocation rearrangement transforms the less stable carbocation into a more stable carbocation to attain greater stability via 1, 2 - hydride shift or 1, 2 - methyl shift. Electrophilic addition reaction proceeds through a carbocation intermediate.

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