(a) Interpretation: The detailed mechanism for the given reaction with major product is to be drawn. Concept introduction: Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone . The acid in aqueous solution gets dissociated and forms hydronium ion H 3 O + . The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

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Can you please help mne with this problem. Im a visual person, so can you redraw it, potentislly color code and then as well explain it. I know im given CO2 use that to explain to me, as well as maybe give me a second example just to clarify even more with drawings (visuals) and explanations.

Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff: Ag₂ CO3 = 2 Ag+ caq) + co} (aq) ksp = 8.10 × 10-12 Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5 a) which salt will precipitate first? (b) What % of the first anion precipitated will remain in the solution. by the time the second anion starts to precipitate? (c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate explanation per answer

Part 4. Butanoic acid (ka= 1.52× 10-5) has a partition coefficient of 3.0 (favors benzene) when distributed bet. water and benzene. What is the formal concentration of butanoic acid in each phase when 0.10M aqueous butanoic acid is extracted w❘ 25 mL of benzene 100 mL of a) at pit 5.00 b) at pH 9.00

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

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Answer 5

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

Answer 6

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Answer 7

Chapter 11, Problem 11.38P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is a isotope of hydrogen atom and reacts like hydrogen.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for the given reaction with major product is to be drawn.

Concept introduction:

Alkynes are electron rich system like alkenes and can undergo electrophilic addition of water in acidic condition to produce the enol form. This enol form, on acid catalyzed tautomerization, converts to a stable keto form, i.e., corresponding aldehyde or ketone. The acid in aqueous solution gets dissociated and forms hydronium ion H3O+. The reaction proceeds with proton transfer reaction to form a stable vinylic carbocation, followed by the action of water as a nucleophile. The deuterium is an isotope of hydrogen atom and reacts like hydrogen.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

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