Principles of General, Organic, Biological Chemistry
Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 11, Problem 11.62AP

(a)

Interpretation Introduction

Interpretation:

Which alkene as a starting material used to prepare 2-butanol has to be determined.

Concept Introduction:

Hydaration reaction is nothing but the addition of water to an alkene.  In this reaction two bonds are simultaneously broken, one is carbon-carbon double bond, and second one is HOH bond, finally forms two  C-H and C-OH bonds. .  The general reaction can be represented as follows,

Principles of General, Organic, Biological Chemistry, Chapter 11, Problem 11.62AP , additional homework tip  1

In the addition of water to an unsymmetrical alknene, the hydrogen from water is bonded to the less substituted carbon atom and is called Markovnikov’s rule.

(b)

Interpretation Introduction

Interpretation:

Which alkene as a starting material used to prepare 2-pentanol has to be determined.

Concept Introduction:

Hydaration reaction is nothing but the addition of water to an alkene.  In this reaction two bonds are simultaneously broken, one is carbon-carbon double bond, and second one is HOH bond, finally forms two  C-H and C-OH bonds. .  The general reaction can be represented as follows,

Principles of General, Organic, Biological Chemistry, Chapter 11, Problem 11.62AP , additional homework tip  2

In the addition of water to an unsymmetrical alknene, the hydrogen from water is bonded to the less substituted carbon atom and is called Markovnikov’s rule.

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Frage

Chapter 11 Solutions

Principles of General, Organic, Biological Chemistry

Ch. 11.3 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Prob. 11.13PCh. 11.6 - Prob. 11.14PCh. 11.6 - Prob. 11.15PCh. 11.7 - Prob. 11.16PCh. 11.7 - Prob. 11.17PCh. 11.9 - Prob. 11.18PCh. 11.9 - Draw the structure corresponding to each name. a....Ch. 11.10 - Prob. 11.20PCh. 11.10 - Prob. 11.21PCh. 11.10 - Prob. 11.22PCh. 11 - Prob. 11.23UKCCh. 11 - Prob. 11.24UKCCh. 11 - Prob. 11.25UKCCh. 11 - Prob. 11.26UKCCh. 11 - Answer the following questions about compound A,...Ch. 11 - Prob. 11.28UKCCh. 11 - Prob. 11.29UKCCh. 11 - Prob. 11.30UKCCh. 11 - Prob. 11.31UKCCh. 11 - Prob. 11.32UKCCh. 11 - Prob. 11.33APCh. 11 - Prob. 11.34APCh. 11 - Prob. 11.35APCh. 11 - Prob. 11.36APCh. 11 - Prob. 11.37APCh. 11 - Falcarinol is a natural pesticide found in carrots...Ch. 11 - Prob. 11.39APCh. 11 - Prob. 11.40APCh. 11 - Prob. 11.41APCh. 11 - Prob. 11.42APCh. 11 - Prob. 11.43APCh. 11 - Give the structure corresponding to each IUPAC...Ch. 11 - Leukotriene C4 is a key compound that causes the...Ch. 11 - Prob. 11.46APCh. 11 - Prob. 11.47APCh. 11 - Prob. 11.48APCh. 11 - Prob. 11.49APCh. 11 - Prob. 11.50APCh. 11 - Prob. 11.51APCh. 11 - Prob. 11.52APCh. 11 - Prob. 11.53APCh. 11 - Prob. 11.54APCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Draw the products formed in each reaction.Ch. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Prob. 11.62APCh. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Prob. 11.72APCh. 11 - Prob. 11.73APCh. 11 - Prob. 11.74APCh. 11 - Prob. 11.75APCh. 11 - Prob. 11.76APCh. 11 - Prob. 11.77APCh. 11 - Prob. 11.78APCh. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - Prob. 11.82APCh. 11 - Prob. 11.83APCh. 11 - Prob. 11.84APCh. 11 - Prob. 11.85APCh. 11 - Prob. 11.86APCh. 11 - Are cis-2-hexene and trans-3-hexene constitutional...Ch. 11 - Prob. 11.88CP
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