(a) Interpretation: How the given compound can be synthesized from two different alkenes is to be shown. Concept introduction: Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Question

The decomposition of dinitrogen pentoxide according to the equation: 50°C 2 N2O5(g) 4 NO2(g) + O2(g) follows first-order kinetics with a rate constant of 0.0065 s-1. If the initial concentration of N2O5 is 0.275 M, determine: the final concentration of N2O5 after 180 seconds. ...

Answer 1

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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The decomposition of dinitrogen pentoxide according to the equation: 50°C 2 N2O5(g) 4 NO2(g) + O2(g) follows first-order kinetics with a rate constant of 0.0065 s-1. If the initial concentration of N2O5 is 0.275 M, determine: the final concentration of N2O5 after 180 seconds. ...

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CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?

Answer 2

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 3

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 4

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 5

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 6

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 7

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 10

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 11

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 12

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Answer 23

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains how Bronsted acids add across a C - C double bond. The proton adds to the less substituted carbon of the initial bond so that the most stable carboc

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