The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained. Concept introduction: The electrophilic addition of H + to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step. Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

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Answer 1

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Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

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CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?

CS2(g) → CS(g) + S(g) The rate law is Rate = k [CS2] where k = 1.6 × 10-6 s−1. S Calculate the half-life.

Answer 2

Question

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

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Answer 3

Question

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

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Answer 4

Question

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

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Answer 5

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

Answer 6

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

Answer 7

Chapter 11, Problem 11.31P

Interpretation Introduction

Interpretation:

The complete mechanism for the given reaction is to be drawn, and its regiochemistry is to be explained.

Concept introduction:

The electrophilic addition of H+ to the C=C double bond produces a carbocation intermediate followed by the coordination step. The more stable carbocation proceeds in the coordination step.

Carbocation intermediates are stabilized by electron-donating groups and destabilized by electron-withdrawing groups.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains that the complete mechanism for the given reaction is drawn on the basis of the stability of carbocation intermediates.

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