EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 8220100576379
Author: KARTY
Publisher: PEARSON
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Question
Chapter 11, Problem 11.32P
Interpretation Introduction
Interpretation:
The product for the given step is to be drawn.
Concept introduction:
The electrophilic addition to the C=C double bond produces the carbocation intermediate. The more stable carbocation proceeds in the next coordination step. Carbocation is stabilized by the lone pair of electrons present at the adjacent atom.
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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
Chapter 11 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - Prob. 11.3PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8PCh. 11 - Prob. 11.9PCh. 11 - Prob. 11.10P
Ch. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14PCh. 11 - Prob. 11.15PCh. 11 - Prob. 11.16PCh. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Prob. 11.21PCh. 11 - Prob. 11.22PCh. 11 - Prob. 11.23PCh. 11 - Prob. 11.24PCh. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.32PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - Prob. 11.35PCh. 11 - Prob. 11.36PCh. 11 - Prob. 11.37PCh. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Prob. 11.40PCh. 11 - Prob. 11.41PCh. 11 - Prob. 11.42PCh. 11 - Prob. 11.43PCh. 11 - Prob. 11.44PCh. 11 - Prob. 11.45PCh. 11 - Prob. 11.46PCh. 11 - Prob. 11.47PCh. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - Prob. 11.50PCh. 11 - Prob. 11.51PCh. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - Prob. 11.56PCh. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - Prob. 11.59PCh. 11 - Prob. 11.60PCh. 11 - Prob. 11.61PCh. 11 - Prob. 11.1YTCh. 11 - Prob. 11.2YTCh. 11 - Prob. 11.3YTCh. 11 - Prob. 11.4YTCh. 11 - Prob. 11.5YTCh. 11 - Prob. 11.6YTCh. 11 - Prob. 11.7YTCh. 11 - Prob. 11.8YTCh. 11 - Prob. 11.9YTCh. 11 - Prob. 11.10YTCh. 11 - Prob. 11.11YTCh. 11 - Prob. 11.12YTCh. 11 - Prob. 11.13YTCh. 11 - Prob. 11.14YT
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