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CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Textbook Question
Chapter 11, Problem 11.3P
PRACTICE 11.1 The boiling point of ethanol is 78.4 °C, and the enthalpy change for theconversion of liquid to vapor is
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Additional problems in preparation to Midterm #1:
1.) How can the following compounds be prepared using Diels-Alder reaction:
CH3 O
CN
(a)
(b)
CN
CH3
2.) What is the missing reagent in the shown reaction?
H3C
+ ?
H3C
H3C
CN
H3C
''CN
(၁)
H
3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene.
Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen.
4.) In the shown reaction, which will be the kinetic product and which will be the
thermodynamic product?
H3C
CI
H3C
HCI
H3C
+
5.) Which of the following molecules is aromatic?
(a)
(b)
(c)
H
6.) Which of the following molecules is aromatic?
(a)
(b)
(c)
7.) Write the mechanism for the shown reaction.
+
Ха
AICI 3
CI
8.) Suggest reagents that would convert benzene into the shown compounds.
CI
NO2
-8-6-6-8-a
(a)
(b)
(c)
(d)
(e)
(a)
SO3H
Br
The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;
Chapter 11 Solutions
CHEMISTRY-TEXT
Ch. 11 - Prob. 11.1PCh. 11 - The normal boiling point of water is 100.0 C, and...Ch. 11 - PRACTICE 11.1 The boiling point of ethanol is 78.4...Ch. 11 - APPLY 11.2 Chloroform CHCl3 has Hvap=29.2kJ/mol...Ch. 11 - How much heat is required to convert15.0 g of...Ch. 11 - APPLY 11.4 What is the sign and magnitude of q...Ch. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.8ACh. 11 - Why was a new solvent needed for extracting...Ch. 11 - A fire extinguisher containing carbon dioxide has...
Ch. 11 - Look at the phase diagram of CO2 in Figure11.13,...Ch. 11 - Liquid carbon dioxide is also used as non-toxic...Ch. 11 - For the phase transition CO2(s)CO2(g), predict the...Ch. 11 - A sample of supercritical carbon dioxide was...Ch. 11 - Assume that you have a liquid in a cylinder...Ch. 11 - The phase diagram of a substance is shown below....Ch. 11 - Prob. 11.17CPCh. 11 - Prob. 11.18CPCh. 11 - The following compound undergoes a phase...Ch. 11 - A magnetized needle gently placed on the surface...Ch. 11 - Water flows quickly through the narrow neck of a...Ch. 11 - Predict which substance in each pair has the...Ch. 11 - Prob. 11.23SPCh. 11 - The chemical structure for oleic acid, the primary...Ch. 11 - Prob. 11.25SPCh. 11 - Prob. 11.26SPCh. 11 - The vapor pressure of SiCI4 is 100 mm Hg at 5.4 C,...Ch. 11 - What is the vapor pressure of CS2 in mm Hg at 20.0...Ch. 11 - What is the vapor pressure of SiCI4 in mm Hg at...Ch. 11 - Dichloromethane, CH2CI2, is an organic solvent...Ch. 11 - Prob. 11.31SPCh. 11 - Use the plot you made in Problem 11.30 to find a...Ch. 11 - Prob. 11.33SPCh. 11 - Prob. 11.34SPCh. 11 - Prob. 11.35SPCh. 11 - Prob. 11.36SPCh. 11 - Acetone,acommon laboratorysolvent,has...Ch. 11 - Why is Hvap usually larger than Hfusion ?Ch. 11 - Why is the heat of sublimation, Hsubl, equal to...Ch. 11 - Naphthalene, better known as "mothballs," has bp =...Ch. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - How much energy in kilojoules is needed to heat...Ch. 11 - Prob. 11.47SPCh. 11 - How much energy in kilojoules is released when...Ch. 11 - How much energy in kilojoules is released when...Ch. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.56SPCh. 11 - Oxygen has Tt=54.3K,Pt=1.14mmHg,Tc=154.6K, and...Ch. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Benzene has a melting point of 5.53 C and a...Ch. 11 - Prob. 11.63SPCh. 11 - How many phase transitions did you pass through in...Ch. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Prob. 11.68SPCh. 11 - Prob. 11.69SPCh. 11 - Prob. 11.70SPCh. 11 - Prob. 11.71SPCh. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - For each of the following substances, identify the...Ch. 11 - The chlorofluorocarbon refrigerant...Ch. 11 - Prob. 11.76MPCh. 11 - Prob. 11.77MP
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