Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 11, Problem 11.38E
Interpretation Introduction
Interpretation:
The condensed structural formulas for each of the three structural isomers of
Concept introduction:
The condensed structural formula of the compound represents the arrangement of atoms by showing specific covalent bonds. The expanded structural formula represents the arrangement of atoms by showing all the covalent bonds. The molecular formula represents the atoms and their subscript represents the number of atoms without showing any covalent bonds.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 11 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 11 - Prob. 11.1ECh. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10E
Ch. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - Prob. 11.13ECh. 11 - Prob. 11.14ECh. 11 - What molecular geometry exists when a central...Ch. 11 - Compare the shapes of unhybridized p and...Ch. 11 - Use Example 11.1 and Tables 11.2 and 11.6 to...Ch. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Prob. 11.20ECh. 11 - Prob. 11.21ECh. 11 - Prob. 11.22ECh. 11 - Prob. 11.23ECh. 11 - Write a condensed structural formula for the...Ch. 11 - Write a condensed structural formula for the...Ch. 11 - Write an expanded structural formula for the...Ch. 11 - Prob. 11.27ECh. 11 - Classify each of the following compounds as a...Ch. 11 - Why are different conformations of an alkane not...Ch. 11 - Which of the following pairs represent structural...Ch. 11 - Prob. 11.31ECh. 11 - Prob. 11.32ECh. 11 - Identify the following alkyl groups: a. b....Ch. 11 - Prob. 11.34ECh. 11 - Prob. 11.35ECh. 11 - Draw a condensed structural formula for each of...Ch. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.39ECh. 11 - Prob. 11.40ECh. 11 - The following names are incorrect, according to...Ch. 11 - The following names are incorrect, according to...Ch. 11 - Prob. 11.43ECh. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Draw the structural formulas corresponding to each...Ch. 11 - Prob. 11.47ECh. 11 - Which of the following pairs of cycloalkanes...Ch. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Which of the following cycloalkanes could show...Ch. 11 - Prob. 11.53ECh. 11 - Using the prefix cis- or trans-, name each of the...Ch. 11 - Prob. 11.55ECh. 11 - The compound decane is a straight-chain alkane....Ch. 11 - Explain why alkanes of low molecular weight have...Ch. 11 - Suppose you have a sample of 2-methylhexane and a...Ch. 11 - Identify circle the alkanelike portions of the...Ch. 11 - Prob. 11.60ECh. 11 - Prob. 11.61ECh. 11 - Write a balanced equation for the incomplete...Ch. 11 - Prob. 11.63ECh. 11 - Prob. 11.64ECh. 11 - Prob. 11.65ECh. 11 - Prob. 11.66ECh. 11 - Prob. 11.67ECh. 11 - Prob. 11.68ECh. 11 - Would you expect a molecule of urea produced in...Ch. 11 - Prob. 11.70ECh. 11 - Prob. 11.71ECh. 11 - Prob. 11.72ECh. 11 - Prob. 11.73ECh. 11 - Prob. 11.74ECh. 11 - Prob. 11.75ECh. 11 - A semi-truck loaded with cyclohexane overturns...Ch. 11 - Prob. 11.77ECh. 11 - Oil spills along coastal shores can be disastrous...Ch. 11 - Prob. 11.79ECh. 11 - Prob. 11.80ECh. 11 - Use the generic formula for alkanes (CnH2n+2) to...Ch. 11 - Prob. 11.82ECh. 11 - Which of the following is an example of an alkane?...Ch. 11 - Prob. 11.84ECh. 11 - Prob. 11.85ECh. 11 - Prob. 11.86ECh. 11 - The deadly property of carbon monoxide, if...
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