Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 11, Problem 11.82E
Interpretation Introduction
Interpretation:
Among the given statements, the one which is correct for organic compounds is to be stated.
Concept Introduction:
An organic compound consists of carbon and hydrogen. They can be classified as natural or synthetic compounds. Organic compounds also consist of heteroatoms like sulphur, oxygen, and nitrogen. The oxides of carbon like carbon dioxide, carbon monoxide are the examples of inorganic compounds.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
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If the original charge is 500 kg, evaluate;
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g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 11 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 11 - Prob. 11.1ECh. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10E
Ch. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - Prob. 11.13ECh. 11 - Prob. 11.14ECh. 11 - What molecular geometry exists when a central...Ch. 11 - Compare the shapes of unhybridized p and...Ch. 11 - Use Example 11.1 and Tables 11.2 and 11.6 to...Ch. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Prob. 11.20ECh. 11 - Prob. 11.21ECh. 11 - Prob. 11.22ECh. 11 - Prob. 11.23ECh. 11 - Write a condensed structural formula for the...Ch. 11 - Write a condensed structural formula for the...Ch. 11 - Write an expanded structural formula for the...Ch. 11 - Prob. 11.27ECh. 11 - Classify each of the following compounds as a...Ch. 11 - Why are different conformations of an alkane not...Ch. 11 - Which of the following pairs represent structural...Ch. 11 - Prob. 11.31ECh. 11 - Prob. 11.32ECh. 11 - Identify the following alkyl groups: a. b....Ch. 11 - Prob. 11.34ECh. 11 - Prob. 11.35ECh. 11 - Draw a condensed structural formula for each of...Ch. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.39ECh. 11 - Prob. 11.40ECh. 11 - The following names are incorrect, according to...Ch. 11 - The following names are incorrect, according to...Ch. 11 - Prob. 11.43ECh. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Write the correct IUPAC name for each of the...Ch. 11 - Draw the structural formulas corresponding to each...Ch. 11 - Prob. 11.47ECh. 11 - Which of the following pairs of cycloalkanes...Ch. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Which of the following cycloalkanes could show...Ch. 11 - Prob. 11.53ECh. 11 - Using the prefix cis- or trans-, name each of the...Ch. 11 - Prob. 11.55ECh. 11 - The compound decane is a straight-chain alkane....Ch. 11 - Explain why alkanes of low molecular weight have...Ch. 11 - Suppose you have a sample of 2-methylhexane and a...Ch. 11 - Identify circle the alkanelike portions of the...Ch. 11 - Prob. 11.60ECh. 11 - Prob. 11.61ECh. 11 - Write a balanced equation for the incomplete...Ch. 11 - Prob. 11.63ECh. 11 - Prob. 11.64ECh. 11 - Prob. 11.65ECh. 11 - Prob. 11.66ECh. 11 - Prob. 11.67ECh. 11 - Prob. 11.68ECh. 11 - Would you expect a molecule of urea produced in...Ch. 11 - Prob. 11.70ECh. 11 - Prob. 11.71ECh. 11 - Prob. 11.72ECh. 11 - Prob. 11.73ECh. 11 - Prob. 11.74ECh. 11 - Prob. 11.75ECh. 11 - A semi-truck loaded with cyclohexane overturns...Ch. 11 - Prob. 11.77ECh. 11 - Oil spills along coastal shores can be disastrous...Ch. 11 - Prob. 11.79ECh. 11 - Prob. 11.80ECh. 11 - Use the generic formula for alkanes (CnH2n+2) to...Ch. 11 - Prob. 11.82ECh. 11 - Which of the following is an example of an alkane?...Ch. 11 - Prob. 11.84ECh. 11 - Prob. 11.85ECh. 11 - Prob. 11.86ECh. 11 - The deadly property of carbon monoxide, if...
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