Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with Quick Prep and Student Solutions Manual 24-Months Printed Access Card
3rd Edition
ISBN: 9781305600874
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 11, Problem 11.32PAE
11.32 The following experimental data were obtained for the reaction 2A + 3 B—C + 2D
[A](mol L 1) | [B](mol L ’) | Rate = A(C]/Af (mol L-1 s-1) |
0.127 | 0.15 | 0.033 |
0.127 | 0.30 | 0.132 |
0.255 | 0.15 | 0.066 |
Determine the reaction order for each reactant and the value of the rate constant.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
All structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?
N-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions
between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary
reactions and the corresponding rate constants are as shown below.
Reaction
Rate constant (M¹s¹)
DMA + NH2Cl = DMCA + NH3
k =1.4×10-1, kr = 5.83×10-3
1.28×10-3
DMA + NH2Cl → UDMH
UDMH + NH2Cl → NDMA
->
1.11×10-1
If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the
concentrations of all species at any given reaction time. Please write down the rate equations
for DMA, NH2C1, DMCA, UDMH and NDMA.
You wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide
a dose of 5.0 mg/L TOTOCI as Cl2.
(a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is
based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic
weight: Na 23, O 16, C1 35.5)
(b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you
want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming
that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of
10 N HCl must be added to achieve the goal? (15 pts)
Note that part a) is a bonus question for undergraduate students. If you decide not to work on
this part of the question, you many assume TOTOCI = 7×10-5 M for part b).
Chapter 11 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with Quick Prep and Student Solutions Manual 24-Months Printed Access Card
Ch. 11 - Prob. 1COCh. 11 - . define the rate of a chemical reaction and...Ch. 11 - Prob. 3COCh. 11 - Prob. 4COCh. 11 - . explain the difference between elementary...Ch. 11 - . find the rate law predicted for a particular...Ch. 11 - . use a molecular perspective to explain the...Ch. 11 - Prob. 8COCh. 11 - . explain the role of a catalyst in the design of...Ch. 11 - Prob. 11.1PAE
Ch. 11 - Prob. 11.2PAECh. 11 - In what region of the atmosphere is ozone...Ch. 11 - What are the steps in the Chapman cycle? Explain...Ch. 11 - What is the net chemical reaction associated with...Ch. 11 - At what points in the Chapman cycle do...Ch. 11 - Prob. 11.7PAECh. 11 - Prob. 11.8PAECh. 11 - Prob. 11.9PAECh. 11 - For each of the following, suggest appropriate...Ch. 11 - For each of the following, suggest an appropriate...Ch. 11 - Rank the following in order of increasing reaction...Ch. 11 - Prob. 11.13PAECh. 11 - Candle wax is a mixture of hydrocarbons. In the...Ch. 11 - Prob. 11.15PAECh. 11 - The reaction for the Haber process, the industrial...Ch. 11 - 11.17 Ammonia can react with oxygen to produce...Ch. 11 - The following data were obtained in the...Ch. 11 - Prob. 11.19PAECh. 11 - Experimental data are listed here for the reaction...Ch. 11 - Azomethane, CH3NNCH3, is not a stable compound,...Ch. 11 - Prob. 11.22PAECh. 11 - A reaction has the experimental rate equation Rate...Ch. 11 - Second-order rate constants used in modeling...Ch. 11 - For each of the rate laws below, what is the order...Ch. 11 - 11.26 The reaction of C(Xg) with NO2(g) is second...Ch. 11 - Prob. 11.27PAECh. 11 - Prob. 11.28PAECh. 11 - The hypothetical reaction, A + B —*C, has the rate...Ch. 11 - The rate of the decomposition of hydrogen...Ch. 11 - Prob. 11.31PAECh. 11 - 11.32 The following experimental data were...Ch. 11 - The following experimental data were obtained for...Ch. 11 - 11.34 Rate data were obtained at 25°C for the...Ch. 11 - 11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) +...Ch. 11 - The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a...Ch. 11 - Prob. 11.37PAECh. 11 - Prob. 11.38PAECh. 11 - The decomposition of N2O5 in solution in carbon...Ch. 11 - In Exercise 11.39, if the initial concentration of...Ch. 11 - 11.41 For a drug to be effective in treating an...Ch. 11 - Amoxicillin is an antibiotic packaged as a powder....Ch. 11 - As with any drug, aspirin (acetylsalicylic acid)...Ch. 11 - 11.44 A possible reaction for the degradation of...Ch. 11 - The initial concentration of the reactant in a...Ch. 11 - A substance undergoes first-order decomposition....Ch. 11 - Prob. 11.47PAECh. 11 - 11.48 The following data were collected for the...Ch. 11 - The rate of photodecomposition of the herbicide...Ch. 11 - Prob. 11.50PAECh. 11 - 11.51 Peroxyacetyl nitrate (PAN) has the chemical...Ch. 11 - Prob. 11.52PAECh. 11 - Hydrogen peroxide (H20i) decomposes into water and...Ch. 11 - use the kineticmolecular theory to explain why an...Ch. 11 - The activation energy for the reaction in which...Ch. 11 - The labels on most pharmaceuticals state that the...Ch. 11 - The following rate constants were obtained in an...Ch. 11 - The table below presents measured rate constants...Ch. 11 - Prob. 11.59PAECh. 11 - Prob. 11.60PAECh. 11 - Prob. 11.61PAECh. 11 - Prob. 11.62PAECh. 11 - Can a reaction mechanism ever be proven correct?...Ch. 11 - Prob. 11.64PAECh. 11 - Describe how the Chapman cycle is a reaction...Ch. 11 - Prob. 11.66PAECh. 11 - Prob. 11.67PAECh. 11 - Prob. 11.68PAECh. 11 - The following mechanism is proposed for a...Ch. 11 - 11.64 HBr is oxidized in the following reaction: 4...Ch. 11 - Prob. 11.71PAECh. 11 - If a textbook defined a catalyst as "a substance...Ch. 11 - Prob. 11.73PAECh. 11 - Prob. 11.74PAECh. 11 - What distinguishes homogeneous and heterogeneous...Ch. 11 - Prob. 11.76PAECh. 11 - Based on the kinetic theory of matter, what would...Ch. 11 - Prob. 11.78PAECh. 11 - In Chapter 3, we discussed the conversion of...Ch. 11 - The label on a bottle of 3% (by volume) hydrogen...Ch. 11 - Prob. 11.81PAECh. 11 - Prob. 11.82PAECh. 11 - Prob. 11.83PAECh. 11 - Prob. 11.84PAECh. 11 - Prob. 11.85PAECh. 11 - Prob. 11.86PAECh. 11 - Prob. 11.87PAECh. 11 - Prob. 11.88PAECh. 11 - Prob. 11.89PAECh. 11 - Prob. 11.90PAECh. 11 - Prob. 11.91PAECh. 11 - Prob. 11.92PAECh. 11 - Prob. 11.93PAECh. 11 - Prob. 11.94PAECh. 11 - 11.93 On a particular day, the ozone level in...Ch. 11 - Prob. 11.96PAECh. 11 - The following is a thought experiment. Imagine...Ch. 11 - The following statements relate to the reaction...Ch. 11 - Prob. 11.99PAECh. 11 - Experiments show that the reaction of nitrogen...Ch. 11 - Substances that poison a catalyst pose a major...Ch. 11 - Prob. 11.102PAECh. 11 - Prob. 11.103PAECh. 11 - 11.102 Suppose that you are studying a reaction...Ch. 11 - Prob. 11.105PAECh. 11 - Prob. 11.106PAECh. 11 - Prob. 11.107PAECh. 11 - Prob. 11.108PAECh. 11 - 11.1047 Fluorine often reacts explosively. What...Ch. 11 - Prob. 11.110PAECh. 11 - Prob. 11.111PAECh. 11 - When formic acid is heated, it decomposes to...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Part A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forwardA solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forwardDon't used Ai solutionarrow_forward
- The standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?arrow_forwardClassification of boranes.arrow_forwardWhat is the pH of a solution made by adding 10-2 M sodium benzoate (C6H5COONa) to pure water, taking into account nonideal solute behavior? Benzoate is the conjugate base of benzoic acid (Ka = 6.25×10-5), a common preservative added to food and beverages.arrow_forward
- Show work. don't give Ai generated solutionarrow_forwardBriefly explain the existence of Nb-Nb bond in the alpha-NbI4 compound.arrow_forwardIn the case of isopilianions, briefly state:- why polymeric species with a defined MW are formed.- why the extent of polymerization is different depending on the metal.- why these polyhedra with such special structures are formed.arrow_forward
- A carboxylic acid reacts with water to form a carboxylate ion and H,O+. Complete the reaction. reaction: (CH),CHCH2COOH + H2O (CH), CHCH, COO¯ + H₂O+ Write the IUPAC name of the carboxylate ion formed in the reaction. IUPAC name: BIU X2 SPECIAL GREEK ALPHABET ~ Iarrow_forwardShow work. Don't give Ai generated solutionarrow_forwardA solution contains 10-3 M (NH4)2CO3 plus 10-3 M CaCO3. (NH4+: pKa 9.26) a) Follow the four steps and list the species and equations that would have to be solved to determine the equilibrium solution composition. (15 pts) b) Prepare a log C-pH diagram for the solution. Use a full sheet of graph paper, and show the ranges 1≤ pH < 13 and -10≤ log C≤ -1. (10 pts) c) Use the graphical approach for the solution pH. What is the concentration of all species? (15 pts)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Kinetics: Chemistry's Demolition Derby - Crash Course Chemistry #32; Author: Crash Course;https://www.youtube.com/watch?v=7qOFtL3VEBc;License: Standard YouTube License, CC-BY