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Bundle: General Chemistry, Loose-Leaf Version, 11th + LabSkills PreLabs v2 for Organic Chemistry (powered by OWLv2), 4 terms (24 months) Printed ... for Ebbing/Gammon's General Chemistry, 11th
11th Edition
ISBN: 9781337542630
Author: Darrell Ebbing, Steven D. Gammon
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 11.18QP
What is the coordination number of Cs− in CsCl? of Na− in NaCl? of Zn2− in ZnS?
Expert Solution & Answer
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Students have asked these similar questions
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 11 Solutions
Bundle: General Chemistry, Loose-Leaf Version, 11th + LabSkills PreLabs v2 for Organic Chemistry (powered by OWLv2), 4 terms (24 months) Printed ... for Ebbing/Gammon's General Chemistry, 11th
Ch. 11.2 - The heat of vaporization of ammonia is 23.4...Ch. 11.2 - Shown here is a representation of a closed...Ch. 11.2 - Prob. 11.2ECh. 11.2 - Selenium tetrafluoride, SeF4, is a colorless...Ch. 11.3 - Prob. 11.4ECh. 11.3 - When camping at high altitude, you need to pay...Ch. 11.5 - Consider two liquids, labeled A and B, that are...Ch. 11.5 - List the different intermolecular forces you would...Ch. 11.5 - Arrange the following hydrocarbons in order of...Ch. 11.5 - At the same temperature, methyl chloride, CH3Cl,...
Ch. 11.5 - A common misconception is that the following...Ch. 11.6 - Prob. 11.8ECh. 11.6 - Prob. 11.9ECh. 11.7 - Figure 11.35 shows solid dots (atoms) forming a...Ch. 11.8 - Shown here is a representation of a unit cell for...Ch. 11.9 - Lithium metal has a body-centered cubic structure...Ch. 11.9 - Potassium metal has a body-centered cubic...Ch. 11 - List the different phase transitions that are...Ch. 11 - Describe how you could purify iodine by...Ch. 11 - Prob. 11.3QPCh. 11 - Explain why 15 g of steam at 100C melts more ice...Ch. 11 - Why is the heat of fusion of a substance smaller...Ch. 11 - Explain why evaporation leads to cooling of the...Ch. 11 - Describe the behavior of a liquid and its vapor in...Ch. 11 - Gases that cannot be liquefied at room temperature...Ch. 11 - Prob. 11.9QPCh. 11 - Why does the vapor pressure of a liquid depend on...Ch. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - What is the coordination number of Cs in CsCl? of...Ch. 11 - Explain in words how Avogadros number could be...Ch. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Under the right conditions, hydrogen gas, H2, can...Ch. 11 - An element crystallizes with a simple cubic...Ch. 11 - Intermolecular Forces The following picture...Ch. 11 - Heat and Molecular Behavior Part 1: a Is it...Ch. 11 - Shown here is a curve of the distribution of...Ch. 11 - Consider a substance X with a Hvap = 20.3 kJ/mol...Ch. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Use Figure 11.7 to estimate the boiling point of...Ch. 11 - Use Figure 11.7 to estimate the boiling point of...Ch. 11 - An electric heater coil provided heat to a 15.5-g...Ch. 11 - Prob. 11.42QPCh. 11 - Isopropyl alcohol, CH3CHOHCH3, is used in rubbing...Ch. 11 - Liquid butane, C4H10, is stored in cylinders to be...Ch. 11 - Water at 0C was placed in a dish inside a vessel...Ch. 11 - A quantity of ice at 0.0C was added to 33.6 g of...Ch. 11 - A quantity of ice at 0C is added to 64.3 g of...Ch. 11 - Steam at 100C was passed into a flask containing...Ch. 11 - Chloroform, CHCl3, a volatile liquid, was once...Ch. 11 - Prob. 11.50QPCh. 11 - White phosphorus, P4, is normally a white, waxy...Ch. 11 - Carbon disulfide, CS2 is a volatile, flammable...Ch. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Which of the following substances can be liquefied...Ch. 11 - A tank of gas at 21C has a pressure of 1.0 atm....Ch. 11 - Prob. 11.59QPCh. 11 - Krypton, Kr, has a triple point at 169C and 133...Ch. 11 - Prob. 11.61QPCh. 11 - The heats of vaporization of liquid O2, liquid Ne,...Ch. 11 - For each of the following substances, list the...Ch. 11 - Which of the following compounds would you expect...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Methane, CH4, reacts with chlorine, Cl2, to...Ch. 11 - The halogens form a series of compounds with each...Ch. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - List the following substances in order of...Ch. 11 - Arrange the following compounds in order of...Ch. 11 - Classify each of the following by the type of...Ch. 11 - Classify each of the following by the type of...Ch. 11 - Classify each of the following solid elements as...Ch. 11 - Which of the following do you expect to be...Ch. 11 - Prob. 11.77QPCh. 11 - Arrange the following substances in order of...Ch. 11 - Prob. 11.79QPCh. 11 - On the basis of the description given, classify...Ch. 11 - Prob. 11.81QPCh. 11 - Associate each of the solids BN, P4S3, Pb, and...Ch. 11 - Prob. 11.83QPCh. 11 - How many atoms are there in a body-centered cubic...Ch. 11 - Metallic iron has a body-centered cubic lattice...Ch. 11 - Nickel has a face-centered unit cell with all...Ch. 11 - Copper metal has a face-centered cubic structure...Ch. 11 - Barium metal has a body-centered cubic lattice...Ch. 11 - Gold has cubic crystals whose unit cell has an...Ch. 11 - Chromium forms cubic crystals whose unit cell has...Ch. 11 - Assume X has a body-centered cubic lattice with...Ch. 11 - Lead has a face-centered cubic lattice with all...Ch. 11 - Prob. 11.93QPCh. 11 - Metallic barium has a body-centered cubic...Ch. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Describe the formation of hydrogen bonds in...Ch. 11 - Prob. 11.104QPCh. 11 - Ethylene glycol (CH2OHCH2OH) is a slightly viscous...Ch. 11 - Pentylamine, CH3CH2CH2CH2CH2NH2, is a liquid that...Ch. 11 - Prob. 11.107QPCh. 11 - Prob. 11.108QPCh. 11 - Decide which substance in each of the following...Ch. 11 - Prob. 11.110QPCh. 11 - Iridium metal, Ir, crystallizes in a face-centered...Ch. 11 - The edge length of the unit cell of tantalum...Ch. 11 - Prob. 11.113QPCh. 11 - Rubidium metal has a body-centered cubic structure...Ch. 11 - Calculate the percent of volume that is actually...Ch. 11 - Calculate the percent of volume that is actually...Ch. 11 - For the hydrogen halides and the noble gases, we...Ch. 11 - For the carbon and nitrogen family hydrides, we...Ch. 11 - Prob. 11.119QPCh. 11 - Prob. 11.120QPCh. 11 - Prob. 11.121QPCh. 11 - Prob. 11.122QPCh. 11 - Prob. 11.123QPCh. 11 - Prob. 11.124QPCh. 11 - A geckos toes have been shown to stick to walls...Ch. 11 - Prob. 11.126QPCh. 11 - Prob. 11.127QPCh. 11 - Prob. 11.128QPCh. 11 - Prob. 11.129QPCh. 11 - Prob. 11.130QPCh. 11 - Prob. 11.131QPCh. 11 - Prob. 11.132QPCh. 11 - In an experiment, 20.00 L of dry nitrogen gas, N2,...Ch. 11 - On a particular summer day, the temperature is...Ch. 11 - Prob. 11.135QPCh. 11 - Prob. 11.136QPCh. 11 - Prob. 11.137QPCh. 11 - Prob. 11.138QPCh. 11 - Prob. 11.139QPCh. 11 - Prob. 11.140QPCh. 11 - Rhenium forms a series of solid oxides: Re2O7...Ch. 11 - Shown below is the cubic unit cell of an ionic...Ch. 11 - Prob. 11.143QPCh. 11 - Strontium crystallizes as a face-centered cubic...Ch. 11 - Prob. 11.145QPCh. 11 - Prob. 11.146QPCh. 11 - Prob. 11.147QPCh. 11 - Prob. 11.148QPCh. 11 - Prob. 11.149QPCh. 11 - Prob. 11.150QPCh. 11 - Prob. 11.151QPCh. 11 - Prob. 11.152QPCh. 11 - How much heat must be added to 28.0 g of solid...Ch. 11 - Prob. 11.154QPCh. 11 - Prob. 11.155QPCh. 11 - Prob. 11.156QPCh. 11 - Nanotechnology, or technology utilizing 1100 nm...
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