General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Chapter 11, Problem 11.17PP
Summary Introduction
To discuss:
The bonding between the two strands of
Introduction:
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This deals with synthetic organic chemistry. Please fill in the blanks appropriately.
Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
Chapter 11 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 11 - Prob. 11.1PPCh. 11 - Prob. 11.2PPCh. 11 - Prob. 11.3PPCh. 11 - Prob. 11.4PPCh. 11 - Prob. 11.5PPCh. 11 - Which of the pentose sugars is found in DNA? Which...Ch. 11 - Prob. 11.7PPCh. 11 - Prob. 11.8PPCh. 11 - Prob. 11.9PPCh. 11 - Prob. 11.10PP
Ch. 11 - Prob. 11.11PPCh. 11 - Prob. 11.12PPCh. 11 - Draw the dinucleotide GC that would be found in...Ch. 11 - Prob. 11.14PPCh. 11 - Prob. 11.15PPCh. 11 - Prob. 11.16PPCh. 11 - Prob. 11.17PPCh. 11 - Prob. 11.18PPCh. 11 - Write the base sequence and label the 3 and 5 ends...Ch. 11 - Write the base sequence and label the 3 and 5 ends...Ch. 11 - Prob. 11.21PPCh. 11 - I jst the similarities and differences in the...Ch. 11 - Prob. 11.23PPCh. 11 - Prob. 11.24PPCh. 11 - Prob. 11.25PPCh. 11 - In your own words, define the term translation.Ch. 11 - Prob. 11.27PPCh. 11 - Prob. 11.28PPCh. 11 - Prob. 11.29PPCh. 11 - Prob. 11.30PPCh. 11 - Provide the three-letter amino-acid sequence...Ch. 11 - Provide the three-letter amino-acid sequence...Ch. 11 - Prob. 11.33PPCh. 11 - Prob. 11.34PPCh. 11 - The following portion of DNA is in the template...Ch. 11 - The following portion of DNA is in the template...Ch. 11 - Prob. 11.37PPCh. 11 - In your own words, define a silent mutation.Ch. 11 - Prob. 11.39PPCh. 11 - Consider the following portion of mRNA produced by...Ch. 11 - Prob. 11.41PPCh. 11 - Prob. 11.42PPCh. 11 - Why do viruses need to enter a host cell?Ch. 11 - Prob. 11.44PPCh. 11 - Prob. 11.45PPCh. 11 - It a virus contains viral RNA, a. name the first...Ch. 11 - Prob. 11.47PPCh. 11 - How do nucleoside analogs disrupt the life cycle...Ch. 11 - Prob. 11.49PPCh. 11 - Prob. 11.50PPCh. 11 - Prob. 11.51PPCh. 11 - Describe the structure of a plasmid.Ch. 11 - Prob. 11.53PPCh. 11 - Prob. 11.54PPCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Prob. 11.58APCh. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Write the complementary base sequence for each of...Ch. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Endorphins arc polypeptides that reduce pain. What...Ch. 11 - What is the one-letter amino-acid sequence formed...Ch. 11 - Prob. 11.74APCh. 11 - What is the anticodon on tRNA for each of the...Ch. 11 - a. A base substitution changes a codon for an...Ch. 11 - Prob. 11.77APCh. 11 - Discuss whether or not each of the following is a...Ch. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - List two societal benefits to recombinant DNA...Ch. 11 - Prob. 11.83APCh. 11 - Oxytocin is a small peptide hormone involved in...Ch. 11 - Alpha-melanocyte stimulating hormone (o-MSH) is a...Ch. 11 - a. If the DNA chromosomes of salmon contain 28%...Ch. 11 - A protein aiumm 35 amino acids. How many...Ch. 11 - The DNA double helix can unwind or denature at...Ch. 11 - Prob. 1IA.1QCh. 11 - Prob. 1IA.2QCh. 11 - Prob. 1IA.3QCh. 11 - Prob. 1IA.4QCh. 11 - Prob. 1IA.5QCh. 11 - Prob. 1IA.6QCh. 11 - Prob. 1IA.7QCh. 11 - Prob. 1IA.8QCh. 11 - Prob. 1IA.9QCh. 11 - Prob. 2IA.1QCh. 11 - Prob. 2IA.2QCh. 11 - Prob. 2IA.3QCh. 11 - Prob. 3IA.1QCh. 11 - Prob. 3IA.2QCh. 11 - Prob. 3IA.3QCh. 11 - Prob. 3IA.4QCh. 11 - Prob. 3IA.5QCh. 11 - Prob. 3IA.6QCh. 11 - Prob. 3IA.7QCh. 11 - Prob. 3IA.8QCh. 11 - Prob. 3IA.9QCh. 11 - Prob. 3IA.10QCh. 11 - Prob. 1ICCh. 11 - Prob. 2ICCh. 11 - Prob. 3IC
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- b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppmarrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardRedraw the flowchartarrow_forward
- redraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forward
- What is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forward
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