The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction. Concept introduction: The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

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Answer 1

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

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Answer 2

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

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Answer 3

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

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Answer 4

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

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Answer 5

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

Answer 6

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

Answer 7

Chapter 11, Problem 11.17P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the formation of the major 1, 2-addition and 1, 4-addition products are to be drawn for the given reaction.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to the Markovnikov rule, where the electrophile and a nucleophile get attached to C1 and C2 carbon atoms of an alkene (double bonded carbon atoms). In the 1, 4-addition, an electrophile and a nucleophile get added to C1 and C4 carbon atoms in the alkene. 1, 4-addition results when the carbocation intermediate is resonance stabilized.

Answer 8

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Answer 10

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Answer 11

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains the electrophilic addition reaction in a case of conjugated diene system.

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