ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
2nd Edition
ISBN: 9780393681826
Author: KARTY
Publisher: NORTON
Question
Book Icon
Chapter 11, Problem 11.12P
Interpretation Introduction

(a)

Interpretation:

It is to be determined how the given compound can be produced from an alkene.

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(b)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Interpretation Introduction

(c)

Interpretation:

It is to be determined how the given compound can be produced from an alkene

Concept introduction:

An electrophile is an electron deficient species that is attacked by a nucleophile, which is an electron-rich species. Alkenes can undergo acid-catalyzed hydration reactions in which the alkenes are treated with water in the presence of strong acids. The major product for these reactions is an alcohol. Water adds across the double bonded carbon atoms according to Markovnikov’s rule. The addition of water to an alkene favors the product in which the proton adds to the alkene carbon that is initially bonded to a greater number of hydrogen atoms (to the least substituted carbon atom), thus forming the stable carbocation intermediate. The rearrangement of the carbocation intermediate does not occur in this reaction. Finally, a proton transfer reaction must take place to form an uncharged product.

Blurred answer
Students have asked these similar questions
Choose the Lewis structure for the compound below: H2CCHOCH2CH(CH3)2 HH H :d H H H C. Η H H HH H H H H. H H H HH H H H H H- H H H C-H H H HHHH
Each of the highlighted carbon atoms is connected to hydrogen atoms.
く Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. More... No reaction. Explanation Check O + G 1. Na O Me Click and drag to start drawing a structure. 2. H + 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility 000 Ar P

Chapter 11 Solutions

ORGANIC CHEMISTRY PRINCIPLES & MECHANISM

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning