General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Chapter 11, Problem 11.115QP
Calculate the percent of volume that is actually occupied by spheres in a body-centered cubic lattice of identical spheres You can do this by first relating the radius of a sphere, r, to the length of an edge of a unit cell, l. (Note that the spheres do not touch along an edge but do touch along a diagonal passing through the body-centered sphere.) Then calculate the volume of a unit cell in terms of r. The volume occupied by spheres equals the number of spheres per unit cell times the volume of a sphere (4πr3/3).
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1) The isoamyl acetate report requires eight paragraphs - four for comparison of isoamyl alcohol and isoamyl acetate (one paragraph each devoted to MS, HNMR, CNMR and IR) and four for comparison of acetic acid and isoamyl acetate ((one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of…
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1) The isoamyl acetate report requires eight paragraphs - four for comparison of isoamyl alcohol and isoamyl acetate (one paragraph each devoted to MS, HNMR, CNMR and IR) and four for comparison of acetic acid and isoamyl acetate ((one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of…
Chapter 11 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 11.2 - The heat of vaporization of ammonia is 23.4...Ch. 11.2 - Shown here is a representation of a closed...Ch. 11.2 - Prob. 11.2ECh. 11.2 - Selenium tetrafluoride, SeF4, is a colorless...Ch. 11.3 - Prob. 11.4ECh. 11.3 - When camping at high altitude, you need to pay...Ch. 11.5 - Consider two liquids, labeled A and B, that are...Ch. 11.5 - List the different intermolecular forces you would...Ch. 11.5 - Arrange the following hydrocarbons in order of...Ch. 11.5 - At the same temperature, methyl chloride, CH3Cl,...
Ch. 11.5 - A common misconception is that the following...Ch. 11.6 - Prob. 11.8ECh. 11.6 - Prob. 11.9ECh. 11.7 - Figure 11.35 shows solid dots (atoms) forming a...Ch. 11.8 - Shown here is a representation of a unit cell for...Ch. 11.9 - Lithium metal has a body-centered cubic structure...Ch. 11.9 - Potassium metal has a body-centered cubic...Ch. 11 - List the different phase transitions that are...Ch. 11 - Describe how you could purify iodine by...Ch. 11 - Prob. 11.3QPCh. 11 - Explain why 15 g of steam at 100C melts more ice...Ch. 11 - Why is the heat of fusion of a substance smaller...Ch. 11 - Explain why evaporation leads to cooling of the...Ch. 11 - Describe the behavior of a liquid and its vapor in...Ch. 11 - Gases that cannot be liquefied at room temperature...Ch. 11 - Prob. 11.9QPCh. 11 - Why does the vapor pressure of a liquid depend on...Ch. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - What is the coordination number of Cs in CsCl? of...Ch. 11 - Explain in words how Avogadros number could be...Ch. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Under the right conditions, hydrogen gas, H2, can...Ch. 11 - An element crystallizes with a simple cubic...Ch. 11 - Intermolecular Forces The following picture...Ch. 11 - Heat and Molecular Behavior Part 1: a Is it...Ch. 11 - Shown here is a curve of the distribution of...Ch. 11 - Consider a substance X with a Hvap = 20.3 kJ/mol...Ch. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Use Figure 11.7 to estimate the boiling point of...Ch. 11 - Use Figure 11.7 to estimate the boiling point of...Ch. 11 - An electric heater coil provided heat to a 15.5-g...Ch. 11 - Prob. 11.42QPCh. 11 - Isopropyl alcohol, CH3CHOHCH3, is used in rubbing...Ch. 11 - Liquid butane, C4H10, is stored in cylinders to be...Ch. 11 - Water at 0C was placed in a dish inside a vessel...Ch. 11 - A quantity of ice at 0.0C was added to 33.6 g of...Ch. 11 - A quantity of ice at 0C is added to 64.3 g of...Ch. 11 - Steam at 100C was passed into a flask containing...Ch. 11 - Chloroform, CHCl3, a volatile liquid, was once...Ch. 11 - Prob. 11.50QPCh. 11 - White phosphorus, P4, is normally a white, waxy...Ch. 11 - Carbon disulfide, CS2 is a volatile, flammable...Ch. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Which of the following substances can be liquefied...Ch. 11 - A tank of gas at 21C has a pressure of 1.0 atm....Ch. 11 - Prob. 11.59QPCh. 11 - Krypton, Kr, has a triple point at 169C and 133...Ch. 11 - Prob. 11.61QPCh. 11 - The heats of vaporization of liquid O2, liquid Ne,...Ch. 11 - For each of the following substances, list the...Ch. 11 - Which of the following compounds would you expect...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Methane, CH4, reacts with chlorine, Cl2, to...Ch. 11 - The halogens form a series of compounds with each...Ch. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - List the following substances in order of...Ch. 11 - Arrange the following compounds in order of...Ch. 11 - Classify each of the following by the type of...Ch. 11 - Classify each of the following by the type of...Ch. 11 - Classify each of the following solid elements as...Ch. 11 - Which of the following do you expect to be...Ch. 11 - Prob. 11.77QPCh. 11 - Arrange the following substances in order of...Ch. 11 - Prob. 11.79QPCh. 11 - On the basis of the description given, classify...Ch. 11 - Prob. 11.81QPCh. 11 - Associate each of the solids BN, P4S3, Pb, and...Ch. 11 - Prob. 11.83QPCh. 11 - How many atoms are there in a body-centered cubic...Ch. 11 - Metallic iron has a body-centered cubic lattice...Ch. 11 - Nickel has a face-centered unit cell with all...Ch. 11 - Copper metal has a face-centered cubic structure...Ch. 11 - Barium metal has a body-centered cubic lattice...Ch. 11 - Gold has cubic crystals whose unit cell has an...Ch. 11 - Chromium forms cubic crystals whose unit cell has...Ch. 11 - Assume X has a body-centered cubic lattice with...Ch. 11 - Lead has a face-centered cubic lattice with all...Ch. 11 - Prob. 11.93QPCh. 11 - Metallic barium has a body-centered cubic...Ch. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Describe the formation of hydrogen bonds in...Ch. 11 - Prob. 11.104QPCh. 11 - Ethylene glycol (CH2OHCH2OH) is a slightly viscous...Ch. 11 - Pentylamine, CH3CH2CH2CH2CH2NH2, is a liquid that...Ch. 11 - Prob. 11.107QPCh. 11 - Prob. 11.108QPCh. 11 - Decide which substance in each of the following...Ch. 11 - Prob. 11.110QPCh. 11 - Iridium metal, Ir, crystallizes in a face-centered...Ch. 11 - The edge length of the unit cell of tantalum...Ch. 11 - Prob. 11.113QPCh. 11 - Rubidium metal has a body-centered cubic structure...Ch. 11 - Calculate the percent of volume that is actually...Ch. 11 - Calculate the percent of volume that is actually...Ch. 11 - For the hydrogen halides and the noble gases, we...Ch. 11 - For the carbon and nitrogen family hydrides, we...Ch. 11 - Prob. 11.119QPCh. 11 - Prob. 11.120QPCh. 11 - Prob. 11.121QPCh. 11 - Prob. 11.122QPCh. 11 - Prob. 11.123QPCh. 11 - Prob. 11.124QPCh. 11 - A geckos toes have been shown to stick to walls...Ch. 11 - Prob. 11.126QPCh. 11 - Prob. 11.127QPCh. 11 - Prob. 11.128QPCh. 11 - Prob. 11.129QPCh. 11 - Prob. 11.130QPCh. 11 - Prob. 11.131QPCh. 11 - Prob. 11.132QPCh. 11 - In an experiment, 20.00 L of dry nitrogen gas, N2,...Ch. 11 - On a particular summer day, the temperature is...Ch. 11 - Prob. 11.135QPCh. 11 - Prob. 11.136QPCh. 11 - Prob. 11.137QPCh. 11 - Prob. 11.138QPCh. 11 - Prob. 11.139QPCh. 11 - Prob. 11.140QPCh. 11 - Rhenium forms a series of solid oxides: Re2O7...Ch. 11 - Shown below is the cubic unit cell of an ionic...Ch. 11 - Prob. 11.143QPCh. 11 - Strontium crystallizes as a face-centered cubic...Ch. 11 - Prob. 11.145QPCh. 11 - Prob. 11.146QPCh. 11 - Prob. 11.147QPCh. 11 - Prob. 11.148QPCh. 11 - Prob. 11.149QPCh. 11 - Prob. 11.150QPCh. 11 - Prob. 11.151QPCh. 11 - Prob. 11.152QPCh. 11 - How much heat must be added to 28.0 g of solid...Ch. 11 - Prob. 11.154QPCh. 11 - Prob. 11.155QPCh. 11 - Prob. 11.156QPCh. 11 - Nanotechnology, or technology utilizing 1100 nm...
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