Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 11, Problem 11.10QAP
Interpretation Introduction
Interpretation:
The reason of using internal standards in the quantitative analysis by ICPMS needs to be explained.
Concept introduction:
ICPMS i.e. Inductively Coupled Plasma Mass Spectrometry carries out quantitative analysis at micro concentrations. To maintain the precision and accuracy, it is essential to eliminate or compensate for all possible errors.
To neutralize the systemic random errors, it is mandatory to test an internal standard.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
What are the advantages and disadvantages of using external standards in instrumental analysis?
(3)
In a titration, the % analyte is computed from the following equation:
Vol (titrant) x M (titrant) x MW (analyte)
% analyte =
x 100
Weight (sample)
Calculate the absolute error in the % analyte from the following data.
Vol (titrant)= 38.04 t 0.02 ml
M (titrant)
MW (analyte) = 74.116 t 0.005 mg/mmol
Wt (sample) = 800.0 ± 0.2 mg
= 0.1137 ± 0.0003 mmol/ml
%3!
professor Scimemi has accepted you as a Master’s student and you are involved in a project that studies the cellular basis of neuropsychiatric diseases. For your electrophysiology recordings you have to make a recording solution containing (in mM): 119 NaCl, 2.5 KCl, 2.5 CaCl2, 1 MgCl2, 26.2 NaHCO3, 1 NaH2PO4, 22 glucose. You need 800 ml of it. How much KCl do you need to weigh out? Hint: we only care about KCl here. (MW KCl is 74.55 g/mol
Chapter 11 Solutions
Principles of Instrumental Analysis
Knowledge Booster
Similar questions
- The analysis shows different concentrations based on replicate determinations of Zn in a water sample: 0.754 mg, 0.721 mg, 0.734 mg, 0.731 mg and 0.742 mg. What is the absolute error if the standard solution has 0.750 mg of Zn?arrow_forwardWhat are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?arrow_forwardWas the gradual color change observed when the sodium thiosulfate (Na2S2O3) crystal was added to the aqueous solution of KI/12 in Station Cevidence of a chemical or physical change?arrow_forward
- An excess of 0.34 mg Pb is obtained from an assay test determined in an analysis. What is the percent relative error in ppt if the mass of the sample is 550 g?arrow_forward20.5)arrow_forwardb) A plot of land was explored and found to contain 1,000,000 grams of gold. The average goldconcentration was found to be 0.8 grams per ton. A mine was set up on it and sluice boxes were used as the main gold recovery units and recovered200,000 g of gold from 80% of the ore. The concentration ratio of the sluice boxes was 10,000.The field was mined again. On this occasion bowl concentrators were used. The feed used wasestimated to be 800,000 tons and the concentration ratio of this unit was 20,000. 750,000 grams ofgold was recovered. Calculate the following: i) the Quantity and grade concentrate from the sluice boxes .................. ..................... ii) the quantity and grade of the concentrate from the bowl concentrator plant. .............. iii) the quantity and grade of the material remaining at this location...................................arrow_forward
- Explain the differences between the following calibration methods and why they are needed. a) External standard; b) Standard addition; c) Internal standardarrow_forwardAn analysis of city drinking water for total hardness was done by two students in the laboratory and produced the following results (in ppm CaCO3): Student A: 228.3, 226.4, 226.9, 227.1, and 228.6. Student B: 229.5, 226.1, 230.7, 223.8, and 227.5What is the 95% confidence interval for the mean?arrow_forward(a) How many grams of nickel are contained in 10.0 g of a 10.2 wt% solution of nickel sulfate hexahydrate, NiSO4 ? 6H2O (FM 262.85)? (b) The concentration of this solution is 0.412 M. Find its density.arrow_forward
- phs.blackboard.com/webapps/assessment/take/take.jsp?course_assessment_id%3D 36688_1&course_id%3D_31958 1&content_id%3_1130567_1&- 8r 10 13 140 15 16 20 11 12 17 18 19 20 A Moving to another question will save this response. Quèstion 6 Select the statement that is not supported by the following equation: q=0=(mwater)(Cwater)(ATwater)+ (mmetal)(Cmetal)( ATmetal) The total change in heat is the sum of the changes in heat of water and a metal. Energy is conserved. Energy is transferred between water and a metal. Energy is lost during a calorimetry experiment. A Moving to another question will save this response. hp & %23 9. 6. 00 进3arrow_forwardThe percentage of an additive in gasoline was measured six times with the following results: 0.13; 0.12; 0.16; 0.17; 0.20 and 0.11%. What is the 99% confidence interval for the additive percentage?arrow_forwardThe molarity of a solution is determined by four separate titrations or replicates, where the obtained data was 0.4120, 0.4920, 0.3920, and 0.4320 M. Calculate the standard error of the mean for the above data. O 0.00185 O 0.02160 O 0.43200 O 0.04320 O 0.01080arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning