Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 11, Problem 107AE
Interpretation Introduction
Interpretation:Dissolution of platinum metal in aqua regia but not in either concentrated nitric or hydrochloric acid individually.
Concept introduction:
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Q4: Circle the substrate that gives a single alkene product in a E2 elimination.
CI
CI
Br
Br
Please calculate the chemical shift of each protons
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
'CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Chapter 11 Solutions
Chemical Principles
Ch. 11 - Prob. 1DQCh. 11 - Prob. 2DQCh. 11 - You want to “plate out” nickel metal from a nickel...Ch. 11 - A copper penny can be dissolved in nitric acid but...Ch. 11 - Sketch a cell that forms iron metal from iron(II)...Ch. 11 - Which of the following is the best reducing agent:...Ch. 11 - You are told that metal A is a better reducing...Ch. 11 - Explain the following relationships: G and w, cell...Ch. 11 - Explain why cell potentials are not multiplied by...Ch. 11 - What is the difference between andWhen is equal to...
Ch. 11 - Prob. 11DQCh. 11 - Look up the reduction potential for Fe3+toFe2+ ....Ch. 11 - Prob. 13DQCh. 11 - Is the following statement true or false?...Ch. 11 - What is electrochemistry? What are redox...Ch. 11 - When magnesium metal is added to a beaker of...Ch. 11 - Prob. 17ECh. 11 - How can you construct a galvanic cell from two...Ch. 11 - Prob. 19ECh. 11 - Prob. 20ECh. 11 - Prob. 21ECh. 11 - Consider the following galvanic cells: For each...Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Answer the following questions using data from...Ch. 11 - Prob. 26ECh. 11 - Using data from Table 11.1, place the following in...Ch. 11 - Prob. 28ECh. 11 - Use the table of standard reduction potentials...Ch. 11 - Use the table of standard reduction potentials...Ch. 11 - Prob. 31ECh. 11 - A patent attorney has asked for your advice...Ch. 11 - The free energy change for a reaction G is an...Ch. 11 - The equation also can be applied to...Ch. 11 - Prob. 35ECh. 11 - Glucose is the major fuel for most living cells....Ch. 11 - Direct methanol fuel cells (DMFCs) have shown...Ch. 11 - The overall reaction and standard cell potential...Ch. 11 - Calculate the maximum amount of work that can...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Chlorine dioxide (ClO2) , which is produced by...Ch. 11 - The amount of manganese in steel is determined...Ch. 11 - The overall reaction and equilibrium constant...Ch. 11 - Prob. 45ECh. 11 - Calculate for the reaction...Ch. 11 - A disproportionation reaction involves a substance...Ch. 11 - Calculate for the following half-reaction:...Ch. 11 - For the following half-reaction AlF63+3eAl+6F...Ch. 11 - Prob. 50ECh. 11 - The solubility product for CuI(s) is 1.11012....Ch. 11 - Explain the following statement: determines...Ch. 11 - Calculate the pH of the cathode compartment for...Ch. 11 - Consider the galvanic cell based on the...Ch. 11 - Prob. 55ECh. 11 - Consider the following galvanic cell at 25°C:...Ch. 11 - The black silver sulfide discoloration of...Ch. 11 - Consider the cell described below:...Ch. 11 - Consider the cell described below:...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - What are concentration cells? What is in a...Ch. 11 - A silver concentration cell is set up at 25°C as...Ch. 11 - Consider the concentration cell shown below....Ch. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - An electrochemical cell consists of a nickel metal...Ch. 11 - You have a concentration cell in which the cathode...Ch. 11 - Consider a galvanic cell at standard conditions...Ch. 11 - An electrochemical cell consists of a zinc metal...Ch. 11 - How long will it take to plate out each of the...Ch. 11 - What mass of each of the following substances can...Ch. 11 - It took 2.30 min with a current of 2.00 A to plate...Ch. 11 - The electrolysis of BiO+ produces pure bismuth....Ch. 11 - A single HallHeroult cell (as shown in Fig. 11.22)...Ch. 11 - A factory wants to produce 1.00103 kg barium...Ch. 11 - Why is the electrolysis of molten salts much...Ch. 11 - What reaction will take place at the cathode and...Ch. 11 - What reaction will take place at the cathode and...Ch. 11 - Prob. 81ECh. 11 - a. In the electrolysis of an aqueous solution of...Ch. 11 - A solution at 25°C contains 1.0 M...Ch. 11 - An aqueous solution of an unknown salt of...Ch. 11 - Consider the following half-reactions: A...Ch. 11 - An unknown metal M is electrolyzed. It took 74.1 s...Ch. 11 - Electrolysis of an alkaline earth metal chloride...Ch. 11 - Prob. 88ECh. 11 - What volume of F2 gas, at 25°C and 1.00 atm, is...Ch. 11 - Prob. 90ECh. 11 - In the electrolysis of a sodium chloride solution,...Ch. 11 - What volumes of H2(g)andO2(g) at STP are...Ch. 11 - Copper can be plated onto a spoon by placing the...Ch. 11 - Prob. 94AECh. 11 - Prob. 95AECh. 11 - Prob. 96AECh. 11 - Prob. 97AECh. 11 - Prob. 98AECh. 11 - Prob. 99AECh. 11 - Prob. 100AECh. 11 - Prob. 101AECh. 11 - Prob. 102AECh. 11 - Prob. 103AECh. 11 - Prob. 104AECh. 11 - In 1973 the wreckage of the Civil War ironclad...Ch. 11 - A standard galvanic cell is constructed so that...Ch. 11 - Prob. 107AECh. 11 - Prob. 108AECh. 11 - Prob. 109AECh. 11 - Prob. 110AECh. 11 - Prob. 111AECh. 11 - Prob. 112AECh. 11 - Prob. 113AECh. 11 - Consider a galvanic cell based on the following...Ch. 11 - Prob. 115AECh. 11 - Prob. 116AECh. 11 - Prob. 117AECh. 11 - Prob. 118AECh. 11 - Prob. 119CPCh. 11 - Prob. 120CPCh. 11 - A zinccopper battery is constructed as follows:...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CPCh. 11 - Prob. 125CPCh. 11 - Prob. 126CPCh. 11 - Prob. 127CPCh. 11 - Prob. 128CPCh. 11 - Prob. 129CPCh. 11 - Prob. 130CPCh. 11 - Prob. 131CPCh. 11 - Prob. 132MPCh. 11 - Prob. 133MP
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