Chapter 10.7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The stereo isomeric product should be given, when it is reacts with per oxyacid followed by hydroxide ion.

Concept introduction:

Formation of epoxide:

The alkene can be converted into epoxide, when it is treated with MCPBA (m-chloro per benzoic acid).

${\text{S}}_{\text{N}}2$reaction:

In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.

In ${\text{S}}_{\text{N}}2$ reaction, the reliving of leaving group from reactant and nucleophilic of attack takes place simultaneously.

Reactant and nucleophile are present at the rate determination step.

The order of species involving in ${\text{S}}_{\text{N}}2$ reaction is,

Tertiary < Secondary < Primary

(b)

Interpretation Introduction

Interpretation:

The stereo isomeric product should be given, when it is reacts with per oxyacid followed by hydroxide ion.

Formation of epoxide:

The alkene can be converted to epoxide, when it is treated with MCPBA (m-chloro perbenzoic acid)

${\text{S}}_{\text{N}}2$reaction:

In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.

In ${\text{S}}_{\text{N}}2$ reaction, the reliving of leaving group from reactant and nucleophilic of attack takes place simultaneously.

Reactant and nucleophile are present at the rate determination step.

The order of species involving in ${\text{S}}_{\text{N}}2$ reaction is,

Tertiary < Secondary < Primary

(c)

Interpretation Introduction

Interpretation:

The stereo isomeric product should be given, when it is reacts with per oxyacid followed by hydroxide ion.

Formation of epoxide:

The alkene can be converted to epoxide, when it is treated with MCPBA (m-chloro perbenzoic acid)

${\text{S}}_{\text{N}}2$reaction:

In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.

In ${\text{S}}_{\text{N}}2$ reaction, the reliving of leaving group from reactant and nucleophilic of attack takes place simultaneously.

Reactant and nucleophile are present at the rate determination step.

The order of species involving in ${\text{S}}_{\text{N}}2$ reaction is,

Tertiary < Secondary < Primary

(d)

Interpretation Introduction

Interpretation:

The stereo isomeric product should be given, when it is reacts with per oxyacid followed by hydroxide ion.

Formation of epoxide:

The alkene can be converted to epoxide, when it is treated with MCPBA (m-chloro perbenzoic acid)

${\text{S}}_{\text{N}}2$reaction:

In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.

In ${\text{S}}_{\text{N}}2$ reaction, the reliving of leaving group from reactant and nucleophilic of attack takes place simultaneously.

Reactant and nucleophile are present at the rate determination step.

The order of species involving in ${\text{S}}_{\text{N}}2$ reaction is,

Tertiary < Secondary < Primary