
Concept explainers
a)
Interpretation:
How to prepare tert-butyl chloride from tert-butylalcohol is to be stated.
Concept introduction:
tert-Alcohols when treated with HCl, HBr or HI in ether at 0oC give the corresponding tert-
To state:
How to prepare tert-butyl chloride from tert-butylalcohol.
b)
Interpretation:
How to .prepare 2-bromo-4-methylpentane from the corresponding alcohol is to be stated.
Concept introduction:
A secondary alkyl bromide is required. Secondary alkyl halides can be prepared by treating the alcohol required with PBr3 in ether solution.
To state:
How to prepare 2-bromo-4-methylpentane from the corresponding alcohol.
c)
Interpretation:
How to .prepare 1-bromo-5-methylhexane from the corresponding alcohol is to be stated.
Concept introduction:
A primary alkyl bromide is required. Primary alkyl halides can be prepared by treating the alcohol required with PBr3 in ether solution.
To state:
How to prepare1-bromo-5-methylhexane from the corresponding alcohol.
d)
Interpretation:
How to .prepare 1-fluoro-3,3-dimethylcyclopentane from the corresponding alcohol is to be stated.
Concept introduction:
A secondary alkyl fluoride is required. Secondary alkyl fluorides can be prepared by treating the alcohol required with diethylaminosulphur trifluoride and HF in pyridine.
To state:
How to prepare1-fluoro-3,3-dimethylcyclopentane from the corresponding alcohol.

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Chapter 10 Solutions
OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card for McMurry's Organic Chemistry, 9th
- Predict the major products of this organic reaction. Be sure you use dash and wedge bonds to show stereochemistry where it's important. + ☑ OH 1. TsCl, py .... 文 P 2. t-BuO K Click and drag to start drawing a structure.arrow_forwardConsider this organic reaction: ( Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. Click and drag to start drawing a structure. Х : а ค 1arrow_forwardIn the drawing area below, draw the major products of this organic reaction: If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. 1. NaH 2. CH3Br ? Click and drag to start drawing a structure. No reaction. : ☐ Narrow_forward
- + Predict the major product of the following reaction. : ☐ + ☑ ค OH H₂SO4 Click and drag to start drawing a structure.arrow_forwardConsider this organic reaction: ... OH CI Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. ☐ No Reaction. Click and drag to start drawing a structure. : аarrow_forwardConsider the following reactants: Br Would elimination take place at a significant rate between these reactants? Note for advanced students: by significant, we mean that the rate of elimination would be greater than the rate of competing substitution reactions. yes O no If you said elimination would take place, draw the major products in the upper drawing area. If you said elimination would take place, also draw the complete mechanism for one of the major products in the lower drawing area. If there is more than one major product, you may draw the mechanism that leads to any of them. Major Products:arrow_forward
- Draw one product of an elimination reaction between the molecules below. Note: There may be several correct answers. You only need to draw one of them. You do not need to draw any of the side products of the reaction. OH + ! : ☐ + Х Click and drag to start drawing a structure.arrow_forwardFind one pertinent analytical procedure for each of following questions relating to food safety analysis. Question 1: The presence of lead, mercury and cadmium in canned tuna Question 2: Correct use of food labellingarrow_forwardFormulate TWO key questions that are are specifically in relation to food safety. In addition to this, convert these questions into a requirement for chemical analysis.arrow_forward
- What are the retrosynthesis and forward synthesis of these reactions?arrow_forwardWhich of the given reactions would form meso product? H₂O, H2SO4 III m CH3 CH₂ONa CH3OH || H₂O, H2SO4 CH3 1. LiAlH4, THF 2. H₂O CH3 IVarrow_forwardWhat is the major product of the following reaction? O IV III HCI D = III ა IVarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

