Concept explainers
a)
Interpretation:
The IUPAC name of the
Concept introduction:
The longest continuous carbon chain in the molecule is chosen. The chain is numbered from the end which gives lowest number to the substituent either halo or alkyl group present. If different halogens are present they are numbered and listed in the alphabetical order while writing the name. If same two alternatives exist for different substituents, then the chain is numbered from the end that gives lowest number to the substituent that has alphabetical preference.
To give:
The IUPAC name of the alkyl halide shown.
Answer to Problem 14VC
The alkyl halide given is
Its IUPAC name is cis- 1- chloro-3-methylcyclohexane.
Explanation of Solution
The compound has a cyclohexane ring with a Cl atom on C1 and a methyl on C3 both at equatorial positions. Hence its name is cis- 1- chloro-3-methylcyclohexane.
The IUPAC name of the alkyl halide shown is cis- 1- chloro-3-methylcyclohexane.
b)
Interpretation:
The IUPAC name of the alkyl halide is to be given.
Concept introduction:
The longest continuous carbon chain in the molecule is chosen. The chain is numbered from the end which gives lowest number to the substituent either halo or alkyl group present. If different halogens are present they are numbered and listed in the alphabetical order while writing the name. If same two alternatives exist for different substituents, then the chain is numbered from the end that gives lowest number to the substituent that has alphabetical preference.
To give:
The IUPAC name of the alkyl halide shown.
Answer to Problem 14VC
The alkyl halide given is
Its IUPAC name is 4-chloro-2-methyl-2-heptene.
Explanation of Solution
The compound has a seven carbon straight chain with a double bond between C2 & C3, a Cl atom on C4 and a methyl on C3. Hence its name is 4-chloro-2-methyl-2-heptene.
The IUPAC name of the alkyl halide shown is 4-chloro-2-methyl-2-heptene.
Want to see more full solutions like this?
Chapter 10 Solutions
OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card for McMurry's Organic Chemistry, 9th
- 2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.arrow_forward2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.arrow_forward1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forward
- H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forward
- Suppose 1.76 g of magnesium acetate (Mg (CH3CO2)2) are dissolved in 140. mL of water. Find the composition of the resulting electrolyte solution. In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row. mEq Then, calculate the concentration of each ion in dwrite the concentration in the second column of each row. Be sure you round your answers to the L correct number of significant digits. ion Add Row mEq L x 5arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows.arrow_forwardNonearrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning