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a)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
b)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
c)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
d)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
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Chapter 10 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
- Nonearrow_forward16. Consider the probability distribution p(x) = ax", 0 ≤ x ≤ 1 for a positive integer n. A. Derive an expression for the constant a, to normalize p(x). B. Compute the average (x) as a function of n. C. Compute σ2 = (x²) - (x)², the variance of x, as a function of n.arrow_forward451. Use the diffusion model from lecture that showed the likelihood of mixing occurring in a lattice model with eight lattice sites: Case Left Right A B C Permeable Barrier → and show that with 2V lattice sites on each side of the permeable barrier and a total of 2V white particles and 2V black particles, that perfect de-mixing (all one color on each side of the barrier) becomes increasingly unlikely as V increases.arrow_forward
- 46. Consider an ideal gas that occupies 2.50 dm³ at a pressure of 3.00 bar. If the gas is compressed isothermally at a constant external pressure so that the final volume is 0.500 dm³, calculate the smallest value Rest can have. Calculate the work involved using this value of Rext.arrow_forwardNonearrow_forward2010. Suppose that a 10 kg mass of iron at 20 C is dropped from a heigh of 100 meters. What is the kinetics energy of the mass just before it hits the ground, assuming no air resistance? What is its speed? What would be the final temperature of the mass if all the kinetic energy at impact is transformed into internal energy? The molar heat capacity of iron is Cpp = 25.1J mol-¹ K-1 and the gravitational acceleration constant is 9.8 m s¯² |arrow_forward
- ell last during 7. Write the isotopes and their % abundance of isotopes of i) Cl ii) Br 8. Circle all the molecules that show Molecular ion peak as an odd number? c) NH2CH2CH2NH2 d) C6H5NH2 a) CH³CN b) CH3OHarrow_forwardCalsulate specific heat Dissolution of NaOH ก ง ง Mass of water in cup Final temp. of water + NaOH Initial temp. of water AT Water AH Dissolution NaOH - "CaicuraORT. AH (NaOH)=-AH( 30g (water) 29.0°C 210°C 8°C (82) 100 3.. =1003.20 Conjosarrow_forwardPlease provide throrough analysis to apply into further problems.arrow_forward
- Molecular ion peak: the peak corresponding to the intact morecure (with a positive charge) 4. What would the base peak and Molecular ion peaks when isobutane is subjected to Mass spectrometry? Draw the structures and write the molecular weights of the fragments. 5. Circle most stable cation a) tert-butyl cation b) Isopropyl cation c) Ethyl cation. d)Methyl cationarrow_forwardHow many arrangements are there of 15 indistinguishable lattice gas particles distributed on: a.V = 15 sites b.V = 16 sites c.V = 20 sitesarrow_forwardFor which element is the 3d subshell higher in energy than that 4s subshell? Group of answer choices Zr Ca V Niarrow_forward
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