The difference in the boiling points of the given set of compounds has to be rationalized. Concept Introduction: Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it. Intramolecular force refers to type of bonding between the atoms. Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound. If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low. They are collectively known as “Interparticle forces”. The classification can be summarized as follows – Figure 1 Figure 2 Figure 3 The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points . Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond . Covalent compounds are found as solids and liquids with moderate melting and boiling point . Metallic bond is formed between the metal atoms of an element. Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen . These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids . They exhibit high boiling point . London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature. Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Question

5. Compressibility (6 points total). The isothermal compressibility is a measure of how hard/easy it is to compress an object (how squishy is it?) at constant temperature. It is др defined as Br=-()=-(200²)T' (a) You might wonder why there is a negative sign in this formula. What does it mean when this quantity is positive and what does it mean when this quantity is negative? (b) Derive the formula for the isothermal compressibility of an ideal gas (it is very simple!) (c) Explain under what conditions for the ideal gas the compressibility is higher or lower, and why that makes sense.

Answer 1

Question

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

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Answer 2

Question

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

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Answer 3

Question

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

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Check out sample textbook solution

Answer 4

Question

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

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Answer 5

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 6

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 7

Chapter 10, Problem 41E

a)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 8

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 9

b)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 10

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 11

c)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 12

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 13

d)

Interpretation Introduction

Interpretation:

The difference in the boiling points of the given set of compounds has to be rationalized.

Concept Introduction:

Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.

Intramolecular force refers to type of bonding between the atoms.

Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.

If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.

They are collectively known as “Interparticle forces”. The classification can be summarized as follows –

                                                             Figure 1



                                                               Figure 2

Figure 3

The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.

Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.

London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.

Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.

Answer 14

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Ch. 10 - What are intermolecular forces? How do they differ...Ch. 10 - Define the following terms and describe how each...Ch. 10 - Compare and contrast solids, liquids, and gases.Ch. 10 - Prob. 4RQ Ch. 10 - What is a lattice? What is a unit cell? Describe a...Ch. 10 - What is closest packing? What is the difference...Ch. 10 - Describe, in general, the structures of ionic...Ch. 10 - Prob. 9RQ Ch. 10 - Prob. 10RQ Ch. 10 - Compare and contrast the phase diagrams of water...

Solution Summary: The author explains the difference in the boiling points of a given set of compounds.

Chapter 10 Solutions