A stepwise mechanism for the free-radical chlorination of cyclopropane to form cyclopropyl chloride is to be drawn. Concept introduction: > The breaking of a covalent bond between two atoms in a way that each atom retains one of the electrons from the bond is called homolytic cleavage. > The breaking of a covalent bond between two atoms in a way that one of the atoms retains both the electrons from the bond is called heterolytic cleavage. > The movement of a single electron is shown by a Fishhook arrow and is called as single electron. > Initiation describes the initial step of formation of radicals. > Propagation is the chain of radical reactions. Once the radical formed in the initiation step, it reacts with suitable molecules.

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Chapter 10, Problem 33P

Interpretation Introduction

Interpretation:

A stepwise mechanism for the free-radical chlorination of cyclopropane to form cyclopropyl chloride is to be drawn.

Concept introduction:
>
The breaking of a covalent bond between two atoms in a way that each atom retains one of the electrons from the bond is called homolytic cleavage.
>
The breaking of a covalent bond between two atoms in a way that one of the atoms retains both the electrons from the bond is called heterolytic cleavage.
>
The movement of a single electron is shown by a Fishhook arrow and is called as single electron.
>
Initiation describes the initial step of formation of radicals.
>
Propagation is the chain of radical reactions. Once the radical formed in the initiation step, it reacts with suitable molecules.

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