ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 10, Problem 17P

Use the bond dissociation enthalpy data in Table 10 .1

to calculate ΔH 0 for the reaction

of methane with a bromine atom.

The activation energy for this reaction is 76 kJ/mol (18 .3 kcal/mol) . Sketch a potential

energy diagram for it, labeling reactants, product, and the transition state. Does the

transition state more closely resemble reactants or products?

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Draw the structure of the product of the reaction given the IR and MS data. Spectral analysis of the product reveals: MS: M 150, M-15, M-43 CH.COCI AICI, IR: 3150-3000 cm, 2950-2850 cm and 1700 cm
Part II. Identify whether the two protons in blue are homotopic, enantiopic, diasteriotopic, or heterotopic. a) HO b) Bri H HH c) d) H H H Br 0
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