ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 10, Problem 21P
Interpretation Introduction

Interpretation:

The product formed in of each of the given reactions is to be determined.

Concept introduction:

Photochemical bromination of alkanes follows the free radical mechanism. Bromination reaction is highly selective. The tertiary hydrogens are more easily abstracted than the secondary or primary hydrogens.

For the addition of hydrogen bromide to alkenes is observed via electrophilic of free radical addition. The reaction of HBr to the double bond in presence of hydrogen peroxide is regioselective and it is opposite to Markovnikov’s rule.

A group 1 metals (Li, Na, K) are reducing agent. The metal in presence of ammonia converts alkyne to alkenes via single electrons transfer.

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