The effect of intermolecular forces on rate of evaporation has to be explained. Concept introduction: Evaporation is a phenomenon applicable to liquids. It is defined as the transition from liquid phase to vapor phase in liquids. This transition occurs either by spontaneously without any external energy or in the presence of external energy. The rate of evaporation is affected by various factors. Intermolecular force is defined as the interactions between the components of a substance. The strength of interaction depends upon the type of components. If the components are ions of unlike charges, as in the case of ionic compounds, the interaction is quite strong which is called electrostatic force of attraction. When the components are non-polar neutral molecules, as in the case of covalent compounds, the intermolecular forces present are Van der Waals forces and London dispersion forces. When the components are of polar nature as in the case of polar covalent compounds, there can be hydrogen bonding, dipole-dipole forces acting between them. Each of these forces is not of equal strength. Thus different compounds have different kind of intermolecular forces and hence different properties.
The effect of intermolecular forces on rate of evaporation has to be explained. Concept introduction: Evaporation is a phenomenon applicable to liquids. It is defined as the transition from liquid phase to vapor phase in liquids. This transition occurs either by spontaneously without any external energy or in the presence of external energy. The rate of evaporation is affected by various factors. Intermolecular force is defined as the interactions between the components of a substance. The strength of interaction depends upon the type of components. If the components are ions of unlike charges, as in the case of ionic compounds, the interaction is quite strong which is called electrostatic force of attraction. When the components are non-polar neutral molecules, as in the case of covalent compounds, the intermolecular forces present are Van der Waals forces and London dispersion forces. When the components are of polar nature as in the case of polar covalent compounds, there can be hydrogen bonding, dipole-dipole forces acting between them. Each of these forces is not of equal strength. Thus different compounds have different kind of intermolecular forces and hence different properties.
Solution Summary: The author explains the effect of intermolecular forces on rate of evaporation.
The effect of intermolecular forces on rate of evaporation has to be explained.
Concept introduction:
Evaporation is a phenomenon applicable to liquids. It is defined as the transition from liquid phase to vapor phase in liquids. This transition occurs either by spontaneously without any external energy or in the presence of external energy. The rate of evaporation is affected by various factors.
Intermolecular force is defined as the interactions between the components of a substance. The strength of interaction depends upon the type of components.
If the components are ions of unlike charges, as in the case of ionic compounds, the interaction is quite strong which is called electrostatic force of attraction.
When the components are non-polar neutral molecules, as in the case of covalent compounds, the intermolecular forces present are Van der Waals forces and London dispersion forces.
When the components are of polar nature as in the case of polar covalent compounds, there can be hydrogen bonding, dipole-dipole forces acting between them.
Each of these forces is not of equal strength. Thus different compounds have different kind of intermolecular forces and hence different properties.
(b)
Interpretation Introduction
Interpretation:
The effect of temperature on rate of evaporation has to be explained.
Concept introduction:
Temperature is measure of average kinetic energy possessed by the molecules. Thus, temperature of a substance implies the average kinetic energy possessed by its molecules. Temperature is measured in different scales like Celsius, Kelvin or Fahrenheit. If the freezing point of water is said to be
0oC, the term
0oC indicates the average kinetic energy of water molecules. It implies, the water molecules are not in movement and have almost zero energy in frozen state.
(c)
Interpretation Introduction
Interpretation:
The effect surface area on rate of evaporation has to be explained.
Concept introduction:
Surface area is the region corresponding to the surface of the molecules. It is associated with the size of the molecules. If the size is large, surface area is high. Molecules with high surface area get more exposure to surroundings.
An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell