Chemistry

10th Edition

ISBN: 9781305957404

Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher: Cengage Learning

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Crystal Lattices and Unit Cell

Consider a crystal. The regular and repeating pattern of constituent particles is the most distinguishing feature of crystalline solids. A crystal lattice is formed when these particles are replaced with representative points. The three-dimensional arran…

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Textbook Question

Chapter 10, Problem 71E

The structures of some common crystalline substances are shown below. Show that the net composition of each unit cell corresponds to the correct formula of each substance.

Chapter 10, Problem 71E, The structures of some common crystalline substances are shown below. Show that the net composition

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Chapter 10 Solutions

Chemistry

Ch. 10 - What are intermolecular forces? How do they differ...Ch. 10 - Define the following terms and describe how each...Ch. 10 - Compare and contrast solids, liquids, and gases.Ch. 10 - Prob. 4RQ Ch. 10 - What is a lattice? What is a unit cell? Describe a...Ch. 10 - What is closest packing? What is the difference...Ch. 10 - Describe, in general, the structures of ionic...Ch. 10 - Prob. 9RQ Ch. 10 - Prob. 10RQ Ch. 10 - Compare and contrast the phase diagrams of water...

Ch. 10 - It is possible to balance a paper clip on the...Ch. 10 - Consider a sealed container half-filled with...Ch. 10 - Explain the following: You add 100 mL water to a...Ch. 10 - Prob. 4ALQ Ch. 10 - Prob. 5ALQ Ch. 10 - Why do liquids have a vapor pressure? Do all...Ch. 10 - Prob. 7ALQ Ch. 10 - What is the vapor pressure of water at 100C? How...Ch. 10 - Prob. 9ALQ Ch. 10 - Prob. 10ALQ Ch. 10 - Prob. 11ALQ Ch. 10 - Why is N2 a gas at room temperature? Explain why...Ch. 10 - Prob. 13ALQ Ch. 10 - In the diagram below, which lines represent the...Ch. 10 - Prob. 16Q Ch. 10 - Prob. 17Q Ch. 10 - The conductivity of silicon is enhanced by doping....Ch. 10 - Atoms are assumed to touch in closest packed...Ch. 10 - Define critical temperature and critical pressure....Ch. 10 - Prob. 21Q Ch. 10 - Describe what is meant by a dynamic equilibrium in...Ch. 10 - Prob. 23Q Ch. 10 - Prob. 24Q Ch. 10 - Prob. 25Q Ch. 10 - Prob. 26Q Ch. 10 - When wet laundry is hung on a clothesline on a...Ch. 10 - You have three covalent compounds with three very...Ch. 10 - Prob. 30Q Ch. 10 - Compare and contrast the structures of the...Ch. 10 - Silicon carbide (SiC) is an extremely hard...Ch. 10 - A common prank on college campuses is to switch...Ch. 10 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 10 - Prob. 36Q Ch. 10 - Identify the most important types of interparticle...Ch. 10 - Prob. 38E Ch. 10 - Predict which substance in each of the following...Ch. 10 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 10 - Prob. 41E Ch. 10 - Consider the following electrostatic potential...Ch. 10 - In each of the following groups of substances,...Ch. 10 - Prob. 44E Ch. 10 - The shape of the meniscus of water in a glass tube...Ch. 10 - Prob. 46E Ch. 10 - Hydrogen peroxide (H2O2) is a syrupy liquid with a...Ch. 10 - Carbon diselenide (CSe2) is a liquid at room...Ch. 10 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 10 - The second-order diffraction (n = 2) for a gold...Ch. 10 - A topaz crystal has an interplanar spacing (d) of...Ch. 10 - X rays of wavelength 2.63 were used to analyze a...Ch. 10 - Calcium has a cubic closest packed structure as a...Ch. 10 - Nickel has a face-centered cubic unit cell. The...Ch. 10 - A certain form of lead has a cubic closest packed...Ch. 10 - The density of polonium metal is 9.2 g/cm3. If the...Ch. 10 - You are given a small bar of an unknown metal X....Ch. 10 - A metallic solid with atoms in a face-centered...Ch. 10 - Titanium metal has a body-centered cubic unit...Ch. 10 - Barium has a body-centered cubic structure. If the...Ch. 10 - The radius of gold is 144 pm, and the density is...Ch. 10 - The radius of tungsten is 137 pm and the density...Ch. 10 - What fraction of the total volume of a cubic...Ch. 10 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 10 - Prob. 65E Ch. 10 - Prob. 66E Ch. 10 - Selenium is a semiconductor used in photocopying...Ch. 10 - Prob. 68E Ch. 10 - Prob. 69E Ch. 10 - Prob. 70E Ch. 10 - The structures of some common crystalline...Ch. 10 - The unit cell for nickel arsenide is shown below....Ch. 10 - Cobalt fluoride crystallizes in a closest packed...Ch. 10 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 10 - What is the formula for the compound that...Ch. 10 - Prob. 76E Ch. 10 - A certain metal fluoride crystallizes in such a...Ch. 10 - The structure of manganese fluoride can be...Ch. 10 - The unit cell of MgO is shown below l Does MgO...Ch. 10 - In solid KCl the smallest distance between the...Ch. 10 - The CsCl structure is a simple cubic array of...Ch. 10 - MnO has either the NaCI type structure or the CsCI...Ch. 10 - What type of solid will each of the following...Ch. 10 - What type of solid will each of the following...Ch. 10 - The memory metal, nitinol, is an alloy of nickel...Ch. 10 - Superalloys have been made of nickel and aluminum....Ch. 10 - Perovskite is a mineral containing calcium,...Ch. 10 - A mineral crystallizes in a cubic closest packed...Ch. 10 - Materials containing the elements Y, Ba, Cu, and O...Ch. 10 - The structures of another class of ceramic,...Ch. 10 - Plot the following data and determine Hvap for...Ch. 10 - From the following data for liquid nitric acid,...Ch. 10 - In Breckenridge, Colorado, the typical atmospheric...Ch. 10 - The temperature inside a pressure cooker is 115C....Ch. 10 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 10 - Mercury is the only metal that is a liquid at room...Ch. 10 - A substance, X, has the following properties:...Ch. 10 - Use the heating-cooling curve below to answer the...Ch. 10 - The molar heat of fusion of sodium metal is 2.60...Ch. 10 - Prob. 100E Ch. 10 - What quantity of energy does it take to convert...Ch. 10 - An ice cube tray contains enough water at 22.0C to...Ch. 10 - A 0.250-g chunk of sodium metal is cautiously...Ch. 10 - Prob. 105E Ch. 10 - Prob. 106E Ch. 10 - Prob. 107E Ch. 10 - Prob. 108E Ch. 10 - Prob. 109E Ch. 10 - Consider the following data for xenon: Triple...Ch. 10 - Prob. 111AE Ch. 10 - Consider the following formulas for n-pentane and...Ch. 10 - Some of the physical properties of H2O and D2O are...Ch. 10 - Rationalize the following boiling points:Ch. 10 - Consider the following vapor pressure versus...Ch. 10 - Consider the following enthalpy changes:...Ch. 10 - Consider the following data for an unknown...Ch. 10 - Consider the data for substance X given in...Ch. 10 - Prob. 119AE Ch. 10 - Boron nitride (BN) exists in two forms. The first...Ch. 10 - Prob. 121AE Ch. 10 - Argon has a cubic closest packed structure as a...Ch. 10 - Prob. 123AE Ch. 10 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 10 - Prob. 125AE Ch. 10 - Carbon tetrachloride. CCl4, has a vapor pressure...Ch. 10 - A special vessel (see Fig. 10.45) contains ice and...Ch. 10 - Prob. 128AE Ch. 10 - In regions with dry climates, evaporative coolers...Ch. 10 - Which of the following compound(s) exhibit only...Ch. 10 - Which of the following statements about...Ch. 10 - Prob. 133CWP Ch. 10 - Aluminum has an atomic radius of 143 pm and forms...Ch. 10 - Pyrolusite is a mineral containing manganese ions...Ch. 10 - The structure of the compound K2O is best...Ch. 10 - Prob. 137CWP Ch. 10 - Some ice cubes at 0c with a total mass of 403 g...Ch. 10 - The enthalpy of vaporization for acetone is 32.0...Ch. 10 - Prob. 140CWP Ch. 10 - When I mole of benzene is vaporized at a constant...Ch. 10 - You and a friend each synthesize a compound with...Ch. 10 - Prob. 143CP Ch. 10 - Prob. 144CP Ch. 10 - Consider two different organic compounds, each...Ch. 10 - Rationalize the differences in physical properties...Ch. 10 - Prob. 147CP Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Spinel is a mineral that contains 37.9% aluminum,...Ch. 10 - Mn crystallizes in the same type of cubic unit...Ch. 10 - You are asked to help set up a historical display...Ch. 10 - Some water is placed in a sealed glass container...Ch. 10 - The molar enthalpy of vaporization of water at 373...Ch. 10 - Prob. 155CP Ch. 10 - Rubidium chloride has the sodium chloride...Ch. 10 - Prob. 157IP Ch. 10 - A metal burns in air at 600c under high pressure...Ch. 10 - Prob. 159IP Ch. 10 - General Zod has sold Lex Luthor what Zod claims to...

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