The following statements to be explained by using given phase diagram of Sulphur. Concept Introduction Phase diagram: Under different temperature and pressure, physical states of the substance that are represented in graph are known as phase diagram. The temperature represents in X-axis and pressure in Y-axis. Triple point: For given substance, three phases (solid, liquid and gas) are coexisting in thermodynamic equilibrium at particular temperature and pressure. Critical point: In a phase diagram, a point at which both liquid and gaseous state of the substance having indistinguishable density. Normal melting point: Normal melting point of the solids defined as the temperature at which solid melts at 1 atmospheric pressure . Normal melting point is differing from melting point in which pressure would be defined. Normal boiling point: Normal boiling point of the liquid is defined as the temperature at which liquid boils at 1 atmospheric pressure . Normal boiling point is differing from boiling point in which pressure would be defined.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

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Question

Chapter 10, Problem 106E

Interpretation Introduction

Interpretation: The following statements to be explained by using given phase diagram of Sulphur.

Concept Introduction

Phase diagram: Under different temperature and pressure, physical states of the substance that are represented in graph are known as phase diagram. The temperature represents in X-axis and pressure in Y-axis.

Triple point: For given substance, three phases (solid, liquid and gas) are coexisting in thermodynamic equilibrium at particular temperature and pressure.

Critical point: In a phase diagram, a point at which both liquid and gaseous state of the substance having indistinguishable density.

Normal melting point: Normal melting point of the solids defined as the temperature at which solid melts at 1 atmospheric pressure. Normal melting point is differing from melting point in which pressure would be defined.

Normal boiling point: Normal boiling point of the liquid is defined as the temperature at which liquid boils at 1 atmospheric pressure. Normal boiling point is differing from boiling point in which pressure would be defined.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

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