(a)
Interpretation:
The compound that is soluble in benzene among CCl4 or NaCl should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
(b)
Interpretation:
The compound that is soluble in benzene among hexane (C6 H14 ) or glycerol (CH2 OHCHOHCH2 OH) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
(c)
Interpretation:
The compound that is soluble in benzene among acetic acid (CH3 COOH) or heptanoic acid (C6 H13 COOH) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
(d)
Interpretation:
The compound that is soluble in benzene among HCl or propylchloride (CH3 CH2 CH2 Cl) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
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Chapter 10 Solutions
Chemistry: Principles and Reactions
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-60 Predict which of these covalent compounds is soluble in water. (a) C2H6 (b) CH3OH (c) HF (d) NH3 (e) CCI4arrow_forward6-38 Describe how we would prepare 250 mL of 0.10 M NaOH from solid NaOH and water.arrow_forward
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- Predict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is NaCl more soluble in water or in carbon tetrachloride? (b) Is I2 more soluble in water or in toluene (C6H5CH3)? (c) Is ethanol (C2H5OH) more soluble in hexane or in water? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in ethanol or in benzene (C6H6)?arrow_forwardFluoridation of city water supplies has been practiced in the United States for several decades. It is done by continuously adding sodium fluoride to water as it comes from a reservoir. Assume you live in a medium-sized city of 150,000 people and that 660 L (170 gal) of water is used per person per day. What mass of sodium fluoride (in kilograms) must be added to the water supply each year (365 days) to have the required fluoride concentration of 1 ppm (part per million)that is, 1 kilogram of fluoride per 1 million kilograms of water? (Sodium fluoride is 45.0% fluoride, and water has a density of 1.00 g/cm3.)arrow_forward6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin (C3H8O3) 0.025 M NaBr, and 0.015 M AI(NO3)3 Assume complete dissociation of any salts.arrow_forward
- 6-32 Would you expect the solubility of ammonia gas in water at 2 atm pressure to be: (a) greater than, (b) the same as, or (c) smaller than at 0.5 atm pressure?arrow_forwardPredict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is Br2 more soluble in water or in carbon tetrachloride? (b) Is CaCl2 more soluble in water or in benzene (C6H6)? (c) Is chloroform (CHCl3) more soluble in water or in diethyl ether [(C2H5)2O]? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in water or in benzene (C6H6)?arrow_forwardIndicate which of the following is more soluble in ethanol, C2H5OH: acetic acid, CH3COOH, or stearic acid, C17H35COOH.arrow_forward
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