(a) Interpretation: The compound that is soluble in benzene among CCl 4 or NaCl should be identified. Concept introduction: Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
(a) Interpretation: The compound that is soluble in benzene among CCl 4 or NaCl should be identified. Concept introduction: Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
Solution Summary: The author explains that the compound that is soluble in benzene among CCl 4 or NaCl should be identified.
The compound that is soluble in benzene among CCl4 or NaCl should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
Interpretation Introduction
(b)
Interpretation:
The compound that is soluble in benzene among hexane (C6 H14 ) or glycerol (CH2 OHCHOHCH2 OH) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
Interpretation Introduction
(c)
Interpretation:
The compound that is soluble in benzene among acetic acid (CH3 COOH) or heptanoic acid (C6 H13 COOH) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
Interpretation Introduction
(d)
Interpretation:
The compound that is soluble in benzene among HCl or propylchloride (CH3 CH2 CH2 Cl) should be identified.
Concept introduction:
Solubility depends on the solvent and solute having same intermolecular bonds. Hence, the polar compounds are soluble in a polar solvent and nonpolar compounds are soluble in non-polar solvents.
Heparin is used as an anti-coagulant. A risk of heparin use is thrombocytopenia, or low platelet
count. This risk is minimized with the use of low molecular weight heparins (LMWH), therefore it is
desirable to separate LMWH from higher molecular weight heparins. The method of choice to do
this is molecular exclusion chromatography. Below is a chromatogram from a molecular exclusion
chromatographic run. Peaks ranging from A to J are clearly distinguishable. The heparin mixture
that was analyzed had anywhere from 6 to 30 repeat units of monomer (where the heparin with 30
repeat units would be roughly five times the size of the heparin with six repeat units).
a. Which letter most likely represents the peak with 6 repeat units given these heparin polymers
were separated with molecular exclusion chromatography?
b. Explain your reasoning describing the mechanism of retention in molecular exclusion
chromatography.
100
80
60
60
Relative Abundance
40
40
E
GH
20
20
B
A
36 38 40 42 44 46 48 50
50…