(a) Interpretation: The structure corresponding to the given ( Z ) − 4 − ethylhept − 3 − ene is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. Rules for writing structural formula from IUPAC are: 1. First identify the word root for the given compound. 2. The suffix used in the compound like –ene. 3. Identify the position, location, and number of the substituent bonded to the carbon chain. The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Question

College Chem II CHE 132 Saturated & Unsaturated Hydrocarbons 1. The following compounds are named incorrectly. Draw the structure of each compound and give it a correct IUPAC name. a) 2-ethyl-4-methylbutane b) 2-isopropyl-3-ethylpentane Hs C - CH-CH3 ansiba C H3- CH - CH-CH2-CH3 A14-ethyl-2,3-dimethyinexane) CH z opanthine CH3 c) 1-propyl-2-ethylbutane CH3 -CH2 - CH- CH2-,CH-CH>-CH; 13-0thylpetane) CHa d) 2,2-diethylpropane e) 3-sec-butylpentane f) 2,4-diethylhexane

Answer 1

Question

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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College Chem II CHE 132 Saturated & Unsaturated Hydrocarbons 1. The following compounds are named incorrectly. Draw the structure of each compound and give it a correct IUPAC name. a) 2-ethyl-4-methylbutane b) 2-isopropyl-3-ethylpentane Hs C - CH-CH3 ansiba C H3- CH - CH-CH2-CH3 A14-ethyl-2,3-dimethyinexane) CH z opanthine CH3 c) 1-propyl-2-ethylbutane CH3 -CH2 - CH- CH2-,CH-CH>-CH; 13-0thylpetane) CHa d) 2,2-diethylpropane e) 3-sec-butylpentane f) 2,4-diethylhexane

Give the IUPAC name for the chemical in the attached image. [click on attachment to view image if you don't see it] CH3CH₂CH₂CH₂CHCH₂CH₂CH₂CH3 CH3CH₂CH₂ O A. 2,2,5,6-tetraethylhexane B. 2,2,5-triethyloctane O C. 3,6-diethyl-3-methylnonane CH₂CH3 D. 3-ethyl-3-methyl-6-propyldecane CH3

identify the functional group of each compound.

Answer 2

Question

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 3

Question

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 4

Question

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

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Answer 5

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 6

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 7

Chapter 10, Problem 10.8P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given (Z)−4−ethylhept−3−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given (E)−3,5,6−trimethyloct−2−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer. The priority order depends upon the atomic number of the elements.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure corresponding to (Z)−2−bromo−1−iodohex−1−ene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing structural formula from IUPAC are:

1. First identify the word root for the given compound.

2. The suffix used in the compound like –ene.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

The use of prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is a Z isomer. The priority order depends upon the atomic number of the elements.

Answer 12

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Answer 23

Ch. 10 - Prob. 10.1P Ch. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Problem 10.3 How many degrees of unsaturation...Ch. 10 - Give the IUPAC name for each alkene. abcde Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Problem 10.6 Label each C-C double bond as E or Z....Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Problem 10.10 Rank the following isomers in order...

Solution Summary: The author explains that the systematic naming of organic compound is given by IUPAC. The structure is correctly interpreted from the name.

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