
Concept explainers
(a)
Interpretation: The constitutional isomer formed by the reaction of given alkene with [1]
Concept introduction: The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of

Answer to Problem 10.29P
The constitutional isomer formed by the reaction of given alkene with
Figure 1
The constitutional isomer formed by the reaction of given alkene with
Figure 2
Explanation of Solution
The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of alkenes is one of the methods used for the formation of alcohol.
Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows Anti-Markovnikov’s rule.
In hydration reactions, the mode of addition is anti-addition, whereas in hydroboration-oxidation, the mode of addition is syn addition.
The given alkene is,
Figure 3
The product formed by the reaction of methylenecyclopentane with
Figure 4
The general steps followed by the hydration reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• Formation of protonated alcohol.
• Deprotonation.
The product formed by the reaction of methylenecyclopentane with
Figure 5
The constitutional isomer formed by the reaction of given alkenes with [1]
(b)
Interpretation: The constitutional isomer formed by the reaction of given alkenes with [1]
Concept introduction: The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of alkenes is one of the methods used for the formation of alcohol.

Answer to Problem 10.29P
The constitutional isomer formed by the reaction of given alkenes with
Figure 6
The constitutional isomer formed by the reaction of given alkenes with
Figure 7
Explanation of Solution
The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of alkenes is one of the methods used for the formation of alcohol.
Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows Anti-Markovnikov’s rule.
In hydration reactions, the mode of addition is anti-addition, whereas in hydroboration-oxidation, the mode of addition is syn addition.
The given alkene is,
Figure 8
The product formed by the reaction of
Figure 9
The general steps followed by the hydration reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• Formation of protonated alcohol.
• Deprotonation.
The product formed by the reaction of
Figure 10
The constitutional isomer formed by the reaction of given alkenes with [1]
(c)
Interpretation: The constitutional isomer formed by the reaction of given alkene with [1]
Concept introduction: The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of alkenes is one of the methods used for the formation of alcohol.

Answer to Problem 10.29P
The constitutional isomer formed by the reaction of given alkene with
Figure 11
The constitutional isomer formed by the reaction of given alkene with
Figure 12
Explanation of Solution
The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomer.
Hydration of alkenes is one of the methods used for the formation of alcohol.
Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows Anti-Markovnikov’s rule.
In hydration reactions, the mode of addition is anti-addition, whereas in hydroboration-oxidation, the mode of addition is syn addition.
The given alkene is,
Figure 13
The product formed by the reaction of methylenecyclopentane with
Figure 14
The general steps followed by the hydration reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• Formation of protonated alcohol.
• Deprotonation.
The product formed by the reaction of methylenecyclopentane with
Figure 15
The constitutional isomer formed by the reaction of given alkenes with [1]
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Chapter 10 Solutions
PKG ORGANIC CHEMISTRY
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