Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Textbook Question
Chapter 10, Problem 10.84EP
What is the medical diagnostic value associated with the presence of each of the following enzymes in the bloodstream?
- a. LDH
- b. AST
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
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mixture to facilitate their separation into different phases. The key to understanding how liquid-
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The following liquid-liquid extraction is different from the one you performed in Experiment
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A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
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b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 10 Solutions
Organic And Biological Chemistry
Ch. 10.1 - Which of the following statements concerning the...Ch. 10.1 - Prob. 2QQCh. 10.2 - Which of the following statements about a...Ch. 10.2 - Which of the following statements about cofactors...Ch. 10.2 - Prob. 3QQCh. 10.3 - Which of the following statements concerning an...Ch. 10.3 - Most enzyme names end with the suffix ase, but a...Ch. 10.3 - Which of the following pairings of enzyme type and...Ch. 10.3 - Which of the following pairings of enzyme type and...Ch. 10.4 - An enzyme active site is the location in an enzyme...
Ch. 10.4 - Which of the following statements concerning the...Ch. 10.4 - Which of the following enzyme properties is...Ch. 10.5 - The specificity of an enzyme that catalyzes the...Ch. 10.5 - Linkage-specific enzymes will act on a particular...Ch. 10.6 - The number of substrate molecules converted to...Ch. 10.6 - Prob. 2QQCh. 10.6 - Prob. 3QQCh. 10.7 - Extremozyme presence is not possible in which of...Ch. 10.7 - Prob. 2QQCh. 10.8 - Which of the following statements concerning a...Ch. 10.8 - Which of the following statements concerning an...Ch. 10.8 - Which of the following binds to an enzyme at a...Ch. 10.9 - Which of the following is an incorrect...Ch. 10.9 - Prob. 2QQCh. 10.9 - Which of the following statements applies to a...Ch. 10.10 - Prob. 1QQCh. 10.10 - Prob. 2QQCh. 10.11 - Prob. 1QQCh. 10.11 - Prob. 2QQCh. 10.12 - Prob. 1QQCh. 10.12 - Prob. 2QQCh. 10.12 - Prob. 3QQCh. 10.13 - Prob. 1QQCh. 10.13 - Which of the following statements about...Ch. 10.13 - In the recharging of a metal-containing enzyme by...Ch. 10.14 - Prob. 1QQCh. 10.14 - Prob. 2QQCh. 10.14 - Prob. 3QQCh. 10.14 - Which of the B vitamins has a name that draws...Ch. 10.14 - Prob. 5QQCh. 10.14 - Prob. 6QQCh. 10.15 - Prob. 1QQCh. 10.15 - Prob. 2QQCh. 10.15 - Prob. 3QQCh. 10.15 - Prob. 4QQCh. 10.15 - Prob. 5QQCh. 10 - What is the general role of enzymes in the human...Ch. 10 - Prob. 10.2EPCh. 10 - List two ways in which enzymes differ from...Ch. 10 - Occasionally the delicate nature of enzymes is...Ch. 10 - Indicate whether each of the following phrases...Ch. 10 - Indicate whether each of the following phrases...Ch. 10 - Prob. 10.7EPCh. 10 - Prob. 10.8EPCh. 10 - Prob. 10.9EPCh. 10 - Prob. 10.10EPCh. 10 - Prob. 10.11EPCh. 10 - Based on its name, indicate whether each of the...Ch. 10 - Predict the function of each of the following...Ch. 10 - Predict the function of each of the following...Ch. 10 - Prob. 10.15EPCh. 10 - What is the substrate for each of the enzymes...Ch. 10 - Suggest a name for an enzyme that catalyzes each...Ch. 10 - Suggest a name for an enzyme that catalyzes each...Ch. 10 - Prob. 10.19EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.21EPCh. 10 - Prob. 10.22EPCh. 10 - Identify the enzyme needed in each of the...Ch. 10 - Identify the enzyme needed in each of the...Ch. 10 - Indicate whether each of the following statements...Ch. 10 - Indicate whether each of the following statements...Ch. 10 - Indicate whether each of the statements in Problem...Ch. 10 - Indicate whether each of the statements in Problem...Ch. 10 - Prob. 10.29EPCh. 10 - Prob. 10.30EPCh. 10 - Prob. 10.31EPCh. 10 - Prob. 10.32EPCh. 10 - Prob. 10.33EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.35EPCh. 10 - Prob. 10.36EPCh. 10 - Prob. 10.37EPCh. 10 - Prob. 10.38EPCh. 10 - What type of specificity (absolute, group,...Ch. 10 - What type of specificity (absolute, group,...Ch. 10 - The following graph shows the relationship between...Ch. 10 - Based on the graphical information in Problem...Ch. 10 - Prob. 10.43EPCh. 10 - Based on the graphical information in Problem...Ch. 10 - Prob. 10.45EPCh. 10 - Prob. 10.46EPCh. 10 - Prob. 10.47EPCh. 10 - Prob. 10.48EPCh. 10 - Prob. 10.49EPCh. 10 - Prob. 10.50EPCh. 10 - Describe the effect that each of the following...Ch. 10 - Prob. 10.52EPCh. 10 - Prob. 10.53EPCh. 10 - Prob. 10.54EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.57EPCh. 10 - Prob. 10.58EPCh. 10 - Prob. 10.59EPCh. 10 - Prob. 10.60EPCh. 10 - Prob. 10.61EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.63EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.65EPCh. 10 - Prob. 10.66EPCh. 10 - Prob. 10.67EPCh. 10 - Prob. 10.68EPCh. 10 - Prob. 10.69EPCh. 10 - What occurs during the covalent modification of an...Ch. 10 - Prob. 10.71EPCh. 10 - Prob. 10.72EPCh. 10 - Explain the difference in meaning, if any, between...Ch. 10 - Prob. 10.74EPCh. 10 - Prob. 10.75EPCh. 10 - Prob. 10.76EPCh. 10 - Prob. 10.77EPCh. 10 - Prob. 10.78EPCh. 10 - Prob. 10.79EPCh. 10 - Prob. 10.80EPCh. 10 - Prob. 10.81EPCh. 10 - What enzyme is denoted by each of the following...Ch. 10 - What is the medical diagnostic value associated...Ch. 10 - What is the medical diagnostic value associated...Ch. 10 - Indicate whether each of the following is a...Ch. 10 - Indicate whether each of the following is a...Ch. 10 - Prob. 10.87EPCh. 10 - Indicate whether each of the vitamins in Problem...Ch. 10 - Prob. 10.89EPCh. 10 - Prob. 10.90EPCh. 10 - Prob. 10.91EPCh. 10 - What are the structural differences between the...Ch. 10 - Prob. 10.93EPCh. 10 - Prob. 10.94EPCh. 10 - Prob. 10.95EPCh. 10 - Prob. 10.96EPCh. 10 - Prob. 10.97EPCh. 10 - Only eight of the nine water-soluble vitamins are...Ch. 10 - Indicate whether each of the following B vitamin...Ch. 10 - Indicate whether each of the following B vitamin...Ch. 10 - Which of the B vitamins has a structure that fits...Ch. 10 - Prob. 10.102EPCh. 10 - Prob. 10.103EPCh. 10 - Prob. 10.104EPCh. 10 - Prob. 10.105EPCh. 10 - Prob. 10.106EPCh. 10 - The coenzyme forms of B vitamins are involved in...Ch. 10 - Prob. 10.108EPCh. 10 - Prob. 10.109EPCh. 10 - What is the relationship between the plant pigment...Ch. 10 - Prob. 10.111EPCh. 10 - Prob. 10.112EPCh. 10 - Prob. 10.113EPCh. 10 - Prob. 10.114EPCh. 10 - Prob. 10.115EPCh. 10 - In terms of their source, how do vitamin D2 and...Ch. 10 - Prob. 10.117EPCh. 10 - Why is vitamin D often called the sunshine...Ch. 10 - Prob. 10.119EPCh. 10 - Prob. 10.120EPCh. 10 - Prob. 10.121EPCh. 10 - Prob. 10.122EPCh. 10 - What is the principal function of vitamin E in the...Ch. 10 - Why is vitamin E often given to premature infants...Ch. 10 - Prob. 10.125EPCh. 10 - Prob. 10.126EPCh. 10 - Prob. 10.127EPCh. 10 - Prob. 10.128EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.131EPCh. 10 - Prob. 10.132EPCh. 10 - Prob. 10.133EPCh. 10 - Which of the 13 vitamins has a structure that fits...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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