ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 10, Problem 10.61AP
Interpretation Introduction

(a)

Interpretation:

The number of electrons involved in the given oxidation reaction is to be stated.

Concept introduction:

The oxidation reaction of primary and secondary alcohol to aldehyde and ketones in the presence of oxalyl chloride, DMSO and organic base triethylamine. The reaction is known by Swern Oxidation. It also gives carbon monoxide, carbon dioxide, and methyl sulfide as side products.

Interpretation Introduction

(b)

Interpretation:

The oxidizing agent used in this reaction is to be stated.

Concept introduction:

The oxidation reaction of primary and secondary alcohol to aldehyde and ketones in the presence of oxalyl chloride, DMSO and organic base triethylamine. The reaction is known by Swern Oxidation. It also gives carbon monoxide, carbon dioxide, and methyl sulfide as side products.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism that accounts for isotopic substitution in the products from the reaction of intermediate A and triethylamine is to be stated.

Concept introduction:

The oxidation reaction of primary and secondary alcohol to aldehyde and ketones in the presence of oxalyl chloride, DMSO and organic base triethylamine. The reaction is known by Swern Oxidation. It also gives carbon monoxide, carbon dioxide, and methyl sulfide as side products.

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Chapter 10 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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