ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 10, Problem 10.36P
Interpretation Introduction

(a)

Interpretation:

The number of electrons involved in the oxidation of triphenyl phosphine to triphenyl phosphine oxide is to be stated.

Concept introduction:

The oxidation is the process of the increase in the oxidation number of the element. This can be done by addition of oxygen, removal of hydrogen and lose of electrons. The number of electrons involved in the oxidation is equal to the change in the oxidation number of the element.

Interpretation Introduction

(b)

Interpretation:

The resonance structures of triphenylphosphine oxide in which it obeys octet rule are to be stated.

Concept introduction:

Resonance is the phenomena of the delocalization of pi electrons to give extra stability to the molecule. This extra stability comes from the distribution of the energy of the molecule in the resonance structures formed.

Interpretation Introduction

(c)

Interpretation:

Lewis structure for trimethylamine oxide (Me3NO) is to be stated. An explanation as to why bond order of the N—O bond in Me3NO compound different from the bond order of the P—O bond in the trimethylphosphine oxide is to be stated.

Concept introduction:

Lewis structure is the electron dot model of the compound showing each pair of electrons between the two atoms leading to the formation of one covalent bond.

Lewis diagrams follow the octet rule when drawn. That is, the total number of electrons around each can be a maximum of eight.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 10 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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