ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 10, Problem 10.6P
Interpretation Introduction

Interpretation:

The structure of the carbocation intermediate involved in the acid-catalyzed dehydration of 3-ethyl-3-pentanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 10 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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