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Science Chemistry Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Appropriate curved arrows are to be provided; the enolate anion is to be labelled, and the type of elementary step is to be recognized by writing “proton transfer” or “S N 2” below each reaction arrow. Concept introduction: When an aldehyde (RCH=O) or ketone (R2C=O) is treated with an alkyl halide alone, no reaction occurs. When a strong base like sodium hydride (NaH) or sodium amide (NaNH 2 ) is added first, however, alkylation can take place at the α carbon (i.e., at the C atom adjacent to the C=O group).

Appropriate curved arrows are to be provided; the enolate anion is to be labelled, and the type of elementary step is to be recognized by writing “proton transfer” or “S N 2” below each reaction arrow. Concept introduction: When an aldehyde (RCH=O) or ketone (R2C=O) is treated with an alkyl halide alone, no reaction occurs. When a strong base like sodium hydride (NaH) or sodium amide (NaNH 2 ) is added first, however, alkylation can take place at the α carbon (i.e., at the C atom adjacent to the C=O group).

Solution Summary: The author explains that alkylation of an aldehyde or ketone can be carried out using proton transfer.

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

2nd Edition

ISBN: 9780393655551

Author: KARTY, Joel

Publisher: W. W. Norton & Company

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Chapter 10, Problem 10.5YT

Interpretation Introduction

Interpretation:

Appropriate curved arrows are to be provided; the enolate anion is to be labelled, and the type of elementary step is to be recognized by writing “proton transfer” or “S_N2” below each reaction arrow.

Concept introduction:

When an aldehyde (RCH=O) or ketone (R2C=O) is treated with an alkyl halide alone, no reaction occurs. When a strong base like sodium hydride (NaH) or sodium amide (NaNH₂) is added first, however, alkylation can take place at the α carbon (i.e., at the C atom adjacent to the C=O group).

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Chapter 10, Problem 10.4YT

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Chapter 10 Solutions

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

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