Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 10, Problem 10.58P
Following is the structural formula of acetamide.
H O
H — C—C— N— H
I
I
H
H
Acetamide (an amide >
- Complete the Lewis structure for acetamide, showing all valence electrons.
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Using your general knowledge of periodic trends in electronegativity, predict whether the C=O bond and the C-H bonds in formaldehyde will be strongly polar, weakly polar or nonpolar.
Calculate the electronegativity difference ΔχO-C across the C=O bond and the electronegativity difference ΔχC-H to confirm or correct your predictions.
For any strongly polar bond(s) on the molecule, draw the bond dipole moment adjacent to the bond in the VSEPR structure above, using crossed arrow notation to show the direction of the positive and negative bond dipoles.
Predict whether the overall molecule should be polar or nonpolar. ___________________ Explain your reasoning below. If the overall molecule is polar, draw the net dipole next to the molecule, using crossed arrow notation to indicate the direction of the dipole.
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of the compound and molecules of water.
compound
hydrogen-bonding force
Between
Between molecules of
formula or Lewis
the compound and
molecules of water?
name
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structure
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H
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yes
|
H – c=N– H
methanimine
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methylamine
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dichloromethane
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O O
H- Z:
Chapter 10 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 10.3 - Prob. 10.1PCh. 10.4 - Prob. 10.2PCh. 10.4 - Prob. 10.3PCh. 10.4 - Prob. 10.4PCh. 10.4 - Prob. 10.5PCh. 10.4 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - 10-9 Is there any difference between vanillin made...Ch. 10 - Prob. 10.10P
Ch. 10 - 10-11 What important experiment did Wohler carry...Ch. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - 10-15 How many electrons are in the valence shell...Ch. 10 - 10-16 What is the relationship between the number...Ch. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - 10-19 Write Lewis structures for these ions. (a)...Ch. 10 - 10-20 Why are the following molecular formulas...Ch. 10 - 10-21 Explain how to use the valence-shell...Ch. 10 - 10-22 Suppose you forget to take into account the...Ch. 10 - Suppose you forget to take into account the...Ch. 10 - 10-24 Use the VSEPR model to predict the bond...Ch. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - 10-27 What is meant by the term functional group?Ch. 10 - 10-28 List three reasons why functional groups are...Ch. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - 10-32 Draw a structural formula for the one...Ch. 10 - 10-33 What is the meaning of the term tertiary (...Ch. 10 - Prob. 10.34PCh. 10 - Draw structural formulas for each of the...Ch. 10 - 10-36 Draw structural formulas for the six ketones...Ch. 10 - 10-37 Draw structural formulas for the eight...Ch. 10 - Prob. 10.38PCh. 10 - 10-39 (Chemical Connections 10A) How was Taxol...Ch. 10 - Prob. 10.40PCh. 10 - Prob. 10.41PCh. 10 - Silicon is immediately below carbon in Group 4A of...Ch. 10 - 10-43 Phosphorus is immediately below nitrogen in...Ch. 10 - Draw the structure for a compound with the...Ch. 10 - 10-45 Draw structural formulas for the eight...Ch. 10 - Prob. 10.46PCh. 10 - 10-47 Which of these covalent bonds are polar, and...Ch. 10 - Of the bonds in Problem 10-47, which is the most...Ch. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Following is a structural formula for naphthalene....Ch. 10 - Prob. 10.52PCh. 10 - Prob. 10.53PCh. 10 - Urea, (NH.,)2CO, is used in plastics and in fertil...Ch. 10 - Prob. 10.55PCh. 10 - Prob. 10.56PCh. 10 - Aspirin is prepared by the reaction of salicylic-...Ch. 10 - Following is the structural formula of acetamide....Ch. 10 - Prob. 10.59P
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- 10-19 Write Lewis structures for these ions. (a) HCOf(b) CO32- Bicarbonate ionCarbonate ion (c) ch3coo-(d)Cr Acetate ionChloride ionarrow_forwardUrea, (NH.,)2CO, is used in plastics and in fertil izers. It is also the primary nitrogen-containing substance excreted by humans. O I I H H Urea Complete the Lewis structure of urea, showing all valence electrons. Predict the bond angle about each C and N. Which is the most polar bond in the molecule? (d, Is urea polar or nonpolar?arrow_forwardUsing the values of electronegativity given in Table 1.5, predict which indicated bond in each set is more polar, and using the symbols + and , show the direction of its polarity. (a) CH3OH or CH3OH (b) CH3NH2 or CH3 PH2 (c) CH3 SH or CH3SH (d) CH3F or HFarrow_forward
- 10-28 List three reasons why functional groups are important in organic chemistry.arrow_forward10-43 Phosphorus is immediately below nitrogen in Group 5A of the Periodic Table. Predict the C—P—C bond angles in trimethylphosphine, (CHaJaP.arrow_forward10-22 Suppose you forget to take into account the presence of the unshared pair of electrons on nitrogen in the molecule NH3. What would you then predict for the H—N—H bond angles and the geometry (bond angles and shape) of ammonia?arrow_forward
- 10-39 (Chemical Connections 10A) How was Taxol discovered?arrow_forwardUse the white balls for hydrogen, the black ones with four points of attachment for carbon, and the red ones wit four points of attachment for oxygen, and the blue ones with four points of attachment for nitrogen. Shape H H-C-H H Methane H-N-H H Ammonia Water Harrow_forwardFor a molecular formula of CsH6O: e a) Draw Lewis structures, showing all bonding and non-bonding electrons, for one compound with an alcohol functional group; one with an ether functional group; one with a ketone functional group; and one with an aldehyde functional group. For each compound, indicate all bond angles and build a molecular model. Indicate whether each pair of valence electrons is non-bonding (n) or o- or л-bonded. For each atom, indicate the corresponding orbitals that are involved (e.g. nsp3, osp3-sp3, etc.). b) c)arrow_forward
- 1A1: Integrate existing knowledge of ionic/covalent bonding, lone pairs, formal charge, valence, and Lewis structures to generate chemically-correct organic building blocks. Examine the given line-angle structure and redraw it, correcting all errors of structure (bonding, lone pairs, formal charge, valence, and the octet rule). 14 H3C. CI- H3C CH3 O H3C B-CH3 N-CH3 CH3arrow_forwardDraw a skeletal ("line") structure of this molecule: O CH3 HỌ—C—CH NH2arrow_forwardProteins are made of amino acids. Given below is the structure of an example of amino acid. What are the two functional groups found in all amino acids? H CH3 | T + H-N-C-C T H H O carboxylate group and methyl group O ammonium group and methyl group O methyl group and thiol group O aldehyde group and ketone group O ammonium group and carboxylate group Oarrow_forward
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