(a) Interpretation: The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated. Concept introduction: The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β - hydrogen from the intermediate.

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Answer 1

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Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

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Answer 3

Question

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

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Answer 4

Question

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

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Answer 5

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Answer 6

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Answer 7

Chapter 10, Problem 10.4P

Interpretation Introduction

(a)

Interpretation:

The alkene formed by the acid-catalyzed dehydration reaction of 3- methyl -3- heptanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done by the acid-catalyzed mechanism. In this mechanism, the first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The alkene(s) formed by the acid-catalyzed dehydration reaction of 1, 2- diphenyl -1- ethanol is to be stated.

Concept introduction:

The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of β- hydrogen from the intermediate.

Answer 10

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Answer 12

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Answer 13

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains how the acid-catalyzed dehydration of alcohol leads to the formation of alkene.

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