ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
Question
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Chapter 10, Problem 10.14P
Interpretation Introduction

(a)

Interpretation:

The complete structure and the abbreviated structure of isopropyl methanesulfonate are to be drawn. The alternate name of isopropyl methanesulfonate is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The complete structure and the abbreviated structure of methyl p- toluenesulfonate are to be drawn. The alternate name of methyl p- toluenesulfonate is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The complete structure and the abbreviated structure of phenyl tosylate are to be drawn. The alternate name of phenyl tosylate is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The complete structure and the abbreviated structure of cyclohexyl mesylate are to be drawn. The alternate name of cyclohexyl mesylate is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

• First identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if same type of substituents are present.

• Name the substituents in alphabetical order.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Chapter 10 Solutions

ORGANIC CHEMISTRY SAPLING ACCESS + ETEX

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