Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Question
Chapter 10, Problem 10.22P
Interpretation Introduction
Interpretation:
To find the ratio of fugacity of steam at initial state to fugacity at the final state from 9000 kPa and 400 0C to 300 kPa.
Concept Introduction :
Gibbs energy is given as below,
and it is related to enthalpy and entropy as given below,
Where,
G = Gibbs Energy
T1 = Initial Temperature = 400 0C
H1 = Initial Enthalpy
S1 = Initial Entropy
f1 = Initial fugacity
T2 = Final Temperature = 400 0C
H2 = Final Enthalpy
S2 = Final Entropy
f2 = Final fugacity
R = Universal Gas constant = 8.314 J/molK
m = Molecular weight = 18 g/mol
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Do question 9 please! Question 7 Is just there for reference!!
7) You are tasked with separating two proteins by ion exchange chromatography on a 30 cm long
column with an inner diameter of 2 cm. The resin has a diameter of 100 μm and a void fraction
of 0.3, and your mobile phase flows through the column at a rate of Q = 5 cm³/min. The Van
Deemter coefficients A, B, and C have been determined to be 0.0228 cm, 0.0036 cm²/min, and
0.00053 min, respectively, for both proteins. Protein A elutes from the column with an average
retention time of 27 min and standard deviation of 0.8 min. Protein B elutes from the column.
with an average retention time of 33.8 min and standard deviation of 1.0.
a) How many theoretical plates does the column contain?
b) What flow rate (Q) will give you the maximum resolution?
c) What is the minimum height of a theoretical plate for the system?
4) A fixed bed adsorption unit contains rigid (incompressible) silica particles with a diameter of
120 um and porosity of 0.3. The resin bed is 200 cm long and has a diameter of 15 cm. A protein
solution is pumped into the column at a rate of 50 L/min, and the mobile phase has a viscosity of
1.2 CP.
a) What is the pressure drop for this system (in bar)?
b) What would be the pressure drop if the particle diameter were decreased to 30 μm?
Chapter 10 Solutions
Introduction to Chemical Engineering Thermodynamics
Ch. 10 - Prob. 10.1PCh. 10 - Prob. 10.2PCh. 10 - Prob. 10.3PCh. 10 - What is the ideal work for the separation of an...Ch. 10 - Prob. 10.5PCh. 10 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - Prob. 10.9PCh. 10 - Prob. 10.10P
Ch. 10 - Prob. 10.11PCh. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - For a particular binary liquid solution at...Ch. 10 - Prob. 10.15PCh. 10 - From the following compressibility-factor data for...Ch. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Prob. 10.22PCh. 10 - Estimate the fugacity of one of the following...Ch. 10 - Prob. 10.24PCh. 10 - Prob. 10.25PCh. 10 - Rationalize the following expression, valid at...Ch. 10 - Prob. 10.27PCh. 10 - Prob. 10.28PCh. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - Prob. 10.32PCh. 10 - Prob. 10.33PCh. 10 - Prob. 10.34PCh. 10 - Prob. 10.35PCh. 10 - The following expressions have been proposed for...Ch. 10 - Prob. 10.37PCh. 10 - Prob. 10.38PCh. 10 - Prob. 10.39PCh. 10 - Prob. 10.40PCh. 10 - Prob. 10.41PCh. 10 - Prob. 10.42PCh. 10 - Prob. 10.43PCh. 10 - Prob. 10.44P
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