How is the geometry of a molecule defined and why is the study of molecular geometry important?
Expert Solution & Answer
Interpretation Introduction
Interpretation:
Molecular geometry and its importance should be explained.
Concept Introduction:
Molecular geometry is the spatial arrangement of the bonded atoms around the central atom. Molecular geometry influences many properties of a molecule.
Explanation of Solution
Molecular geometry is the spatial arrangement of atoms on a molecule and/ or ions.
It is the three dimensional arrangement of the bonded atoms with its central atom.
Several chemical and physical properties like polarity, color, reactivity etc. of a molecule depends on its geometry. Even the biological activity of a drug depends on the molecular geometry.
The geometry of a molecule can be found out by different methods like IR, Raman spectroscopy etc.
Here the position of each atom is determined by the nature of chemical bonding with its neighboring atoms.
We can predict the geometry by using Lewis structure and VSEPR (Valence-Shell Electron Pair Repulsion) model.
Molecular formula alone is not enough for the prediction of molecular geometry. Type of bonding, lone pair etc. depends on its prediction.
For example, the geometry of a molecule with formula AB2 can have either linear or bent.
Conclusion
Molecular geometry and its importance was explained
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21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to
most acidic).
OH
OH
SH
NH2
8
NH3
OH
(b)
OH
OH
OH
(c)
& & &
CH3
NO2
21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol.
OH
OH
OH
OH
PK 10.0
PK 8.81
PK 9.28
PK 9.81
identify which spectrum is for acetaminophen and which is for phenacetin
The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
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