Problem 10.1QP: How is the geometry of a molecule defined and why is the study of molecular geometry important? Problem 10.2QP: Sketch the shape of a linear triatomic molecule, a trigonal planar molecule containing four atoms, a... Problem 10.3QP: How many atoms are directly bonded to the central atom in a tetrahedral molecule, a trigonal... Problem 10.4QP: Discuss the basic features of the VSEPR model. Explain why the magnitude of repulsion decreases in... Problem 10.5QP Problem 10.6QP Problem 10.7QP: Predict the geometries of the following species using the VSEPR method: (a) PCl3, (b) CHCl3, (c)... Problem 10.8QP: Predict the geometries of the following species: (a) AlCl3, (b) ZnCl2, (c) ZnCl42. Problem 10.9QP: Predict the geometry of the following molecules and ion using the VSEPR model: (a) CBr4, (b) BCl3,... Problem 10.10QP: Predict the geometry of the following molecules and ion using the VSEPR model: (a) CH3I, (b) ClF3,... Problem 10.11QP: Predict the geometry of the following molecules using the VSEPR method: (a) HgBr2, (b) N2O... Problem 10.12QP: Predict the geometries of the following ions: (a) NH4+,(b) NH2, (c) CO32, (d) ICl2, (e) ICl4, (f)... Problem 10.13QP: Describe the geometry around each of the three central atoms in the CH3COOH molecule. Problem 10.14QP: Which of the following species are tetrahedral? SiCl4, SeF4, XeF4, CI4, CdCl42 Problem 10.15QP Problem 10.16QP Problem 10.17QP Problem 10.18QP: The bonds in beryllium hydride (BeH2) molecules are polar, and yet the dipole moment of the molecule... Problem 10.19QP: Referring to Table 10.3, arrange the following molecules in order of increasing dipole moment: H2O,... Problem 10.20QP: The dipole moments of the hydrogen halides decrease from HF to HI (see Table 10.3). Explain this... Problem 10.21QP: List the following molecules in order of increasing dipole moment: H2O, CBr4, H2S, HF, NH3, CO2. Problem 10.22QP: Does the molecule OCS have a higher or lower dipole moment than CS2? Problem 10.23QP: Which of the molecules (a) or (b) has a higher dipole moment? Problem 10.24QP Problem 10.25QP: What is valence bond theory? How does it differ from the Lewis concept of chemical bonding? Problem 10.26QP: Use valence bond theory to explain the bonding in Cl2 and HCl. Show how the atomic orbitals overlap... Problem 10.27QP Problem 10.28QP Problem 10.29QP Problem 10.30QP: What is the angle between the following two hybrid orbitals on the same atom? (a) sp and sp hybrid... Problem 10.31QP: Describe the bonding scheme of the AsH3 molecule in terms of hybridization. Problem 10.32QP: What is the hybridization state of Si in SiH4 and in H3SiSiH3? Problem 10.33QP: Describe the change in hybridization (if any) of the Al atom in the following reaction:... Problem 10.34QP: Consider the reaction BF3+NH3F3BNH3 Describe the changes in hybridization (if any) of the B and N... Problem 10.35QP: What hybrid orbitals are used by nitrogen atoms in the following species? (a) NH3, (b) H2N NH2, (c)... Problem 10.36QP Problem 10.37QP: Give the formula of a cation comprised of iodine and fluorine in which the iodine atom is sp3... Problem 10.38QP: Give the formula of an anion comprised of iodine and fluorine in which the iodine atom is sp3... Problem 10.39QP: How would you distinguish between a sigma bond and a pi bond? Problem 10.40QP: What are the hybrid orbitals of the carbon atoms in the following molecules? (a) H3CCH3 (b) H3CCHCH2... Problem 10.41QP: Specify which hybrid orbitals are used by carbon atoms in the following species: (a) CO, (b) CO2,... Problem 10.42QP Problem 10.43QP: The allene molecule H2CCCH2 is linear (the three C atoms lie on a straight line). What are the... Problem 10.44QP: How many pi bonds and sigma bonds are there in the tetracyanoethylene molecule? Problem 10.45QP: How many sigma bonds and pi bonds are there in each of the molecules (a), (b), and (c)? Problem 10.46QP: What is molecular orbital theory? How does it differ from valence bond theory? Problem 10.47QP: Sketch the shapes of the following molecular orbitals: 1s, 1s, 2p, and 2p. How do their energies... Problem 10.48QP: Explain the significance of bond order. Can bond order be used for quantitative comparisons of the... Problem 10.49QP: Explain in molecular orbital terms the changes in HH internuclear distance that occur as the... Problem 10.50QP: The formation of H2 from two H atoms is an energetically favorable process. Yet statistically there... Problem 10.51QP Problem 10.52QP: Arrange the following species in order of increasing stability: Li2, Li2+, Li2. Justify your choice... Problem 10.53QP Problem 10.54QP: Which of these species has a longer bond, B2 or B2+? Explain in terms of molecular orbital theory. Problem 10.55QP: Acetylene (C2H2) has a tendency to lose two protons (H+) and form the carbide ion (C22), which is... Problem 10.56QP: Compare the Lewis and molecular orbital treatments of the oxygen molecule. Problem 10.57QP: Explain why the bond order of N2 is greater than that Of N2+, but the bond order of O2 is less than... Problem 10.58QP: Compare the relative stability of the following species and indicate their magnetic properties (that... Problem 10.59QP: Use molecular orbital theory to compare the relative stabilities of F2 and F2+ Problem 10.60QP: A single bond is almost always a sigma bond, and a double bond is almost always made up of a sigma... Problem 10.61QP: In 2009 the ion N23 was isolated. Use a molecular orbital diagram to compare its properties (bond... Problem 10.62QP: The following potential energy curve represents the formation of F2 from two F atoms. Describe the... Problem 10.63QP Problem 10.64QP Problem 10.65QP Problem 10.66QP: Explain why the symbol on the left is a better representation of benzene molecules than that on the... Problem 10.67QP: Determine which of these molecules has a more delocalized orbital and justify your choice. (Hint:... Problem 10.68QP: Nitryl fluoride (FNO2) is very reactive chemically. The fluorine and oxygen atoms are bonded to the... Problem 10.69QP: Describe the bonding in the nitrate ion NO3 in terms of delocalized molecular orbitals. Problem 10.70QP Problem 10.71QP: Which of the following species is not likely to have a tetrahedral shape? (a) SiBr4, (b) NF4+, (c)... Problem 10.72QP: Draw the Lewis structure of mercury(II) bromide. Is this molecule linear or bent? How would you... Problem 10.73QP: Sketch the bond moments and resultant dipole moments for the following molecules: H2O, PCl3, XeF4,... Problem 10.74QP: Although both carbon and silicon are in Group 4A, very few SiSi bonds are known. Account for the... Problem 10.75QP: Acetaminophen is the active ingredient in Tylenol. (a) Write the molecular formula of the compound.... Problem 10.76QP: Caffeine is a stimulant drug present in coffee. (a) Write the molecular formula of the compound. (b)... Problem 10.77QP: Predict the geometry of sulfur dichloride (SCl2) and the hybridization of the sulfur atom. Problem 10.78QP: Antimony pentafluoride, SbF5, reacts with XeF4 and XeF6 to form ionic compounds, XeF3+SbF6 and... Problem 10.79QP: Draw Lewis structures and give the other information requested for the following molecules: (a) BF3.... Problem 10.80QP: Predict the bond angles for the following molecules: (a) BeCl2, (b) BCl3, (c) CCl4, (d) CH3Cl, (e)... Problem 10.81QP: Briefly compare the VSEPR and hybridization approaches to the study of molecular geometry. Problem 10.82QP: Describe the hybridization state of arsenic in arsenic pentafluoride (AsF5). Problem 10.83QP: Draw Lewis structures and give the other information requested for the following: (a) SO3. Polar or... Problem 10.84QP: Which of the following molecules and ions are linear? ICl2, IF2+, OF2, SnI2, CdBr2. Problem 10.85QP Problem 10.86QP: The N2F2 molecule can exist in either of the following two forms: (a) What is the hybridization of N... Problem 10.87QP: Cyclopropane (C3H6) has the shape of a triangle in which a C atom is bonded to two H atoms and two... Problem 10.88QP: The compound 1,2-dichloroethane (C2H4Cl2) is nonpolar, while cis-dichloroethylene (C2H2Cl2) has a... Problem 10.89QP: Does the following molecule have a dipole moment? (Hint: See the answer to Problem 10.39.) Problem 10.90QP: So-called greenhouse gases, which contribute to global warming, have a dipole moment or can be bent... Problem 10.91QP: The bond angle of SO2 is very close to 120, even though there is a lone pair on S. Explain. Problem 10.92QP: 3-azido-3-deoxythymidine, shown here, commonly known as AZT, is one of the drugs used to treat... Problem 10.93QP: The following molecules (AX4Y2) all have octahedral geometry. Group the molecules that are... Problem 10.94QP: The compounds carbon tetrachloride (CCl4) and silicon tetrachloride (SiCl4) are similar in geometry... Problem 10.95QP Problem 10.96QP: What are the hybridization states of the C and N atoms in this molecule? Problem 10.97QP: Use molecular orbital theory to explain the difference between the bond enthalpies of F2 and F2 (see... Problem 10.98QP: Referring to the Chemistry in Action essay Microwave Ovens-Dipole Moments at Work in Section 10.2,... Problem 10.99QP: Which of the molecules (a)(c) are polar? Problem 10.100QP Problem 10.101QP: The stable allotropic form of phosphorus is P4, in which each P atom is bonded to three other P... Problem 10.102QP: Referring to Table 9.4, explain why the bond enthalpy for Cl2 is greater than that for F2. (Hint:... Problem 10.103QP: Use molecular orbital theory to explain the bonding in the azide ion (N3). (Arrangement of atoms is... Problem 10.104QP: The ionic character of the bond in a diatomic molecule can be estimated by the formula ed100 where ... Problem 10.105QP Problem 10.106QP Problem 10.107QP: Aluminum trichloride (AlCl3) is an electron-deficient molecule. It has a tendency to form a dimer (a... Problem 10.108QP: The molecules cis-dichloroethylene and trans-dichloroethylene shown in Section 10.2 can be... Problem 10.109QP Problem 10.110QP Problem 10.111QP: The molecule benzyne (C6H4) is a very reactive species. It resembles benzene in that it has a... Problem 10.112QP: Assume that the third-period element phosphorus forms a diatomic molecule, P2, in an analogous way... Problem 10.113QP: Consider a N2 molecule in its first excited electronic state, that is, when an electron in the... Problem 10.114QP Problem 10.116QP Problem 10.117QP: Draw the Lewis structure of ketene (C2H2O) and describe the hybridization states of the C atoms. The... Problem 10.118QP: TCDD, or 2,3,7,8-tetrachlorodibenzo-p-dioxin, is a highly toxic compound: It gained considerable... Problem 10.119QP: Write the electron configuration of the cyanide ion (CN). Name a stable molecule that is... Problem 10.120QP Problem 10.121QP: The geometries discussed in this chapter all lend themselves to fairly straightforward elucidation... Problem 10.122QP Problem 10.123QP: Which of the following ions possess a dipole moment: (a) ClF2+, (b) ClF2, (c) IF4+, (d) IF4? Problem 10.124QP: Given that the order of molecular orbitals for NO is similar to that for O2, arrange the following... Problem 10.125QP: Shown here are molecular models of SX4 for X = F, Cl, and Br. Comment on the trends in the bond... Problem 10.126QP: Based on what you have learned from this chapter and Chapter 9, name a diatomic molecule that has... Problem 10.128QP: How many carbon atoms are contained in one square centimeter of graphene? (See the Chemistry in... format_list_bulleted