Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 10, Problem 10.111QE
Interpretation Introduction
Interpretation:
The Lewis structure of phosgene has to be determined and also the hybridization of carbon atom and polarity of the molecule has to be given.
Concept Introduction:
Lewis structure is used for predicting the shape of molecules. From the steric number obtained in a Lewis structure, the molecular geometry can be predicted. VSEPR model can predict the shape of molecules considering their Lewis structure. Certain rules has to be followed in for the VSEPR model.
- The molecule will have a shape where there is minimal electrostatic repulsion between the valence‑shell electron pairs.
- The forces of repulsion between two lone pairs of electrons will be higher than the repulsion between lone pair and bond pair of electrons. This in turn will be higher than the bond pair‑bond pair of electrons.
The hybridized orbitals and the steric number can be related as shown below;
| Steric number | Hybridized orbital |
| 2 | |
| 3 | |
| 4 | |
| 5 |
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How many signals do you expect in the H NMR spectrum for this molecule?
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atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
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to the same signal as the H atom already highlighted red.
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molecule
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Consider this molecule:
How many H atoms are in this molecule?
22
How many different signals could be found in its 'H NMR spectrum?
12
Note: A multiplet is considered one signal.
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O
signal(s)
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'C NMR spectrum for the following compound?
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Chapter 10 Solutions
Chemistry Principles And Practice
Ch. 10 - Prob. 10.1QECh. 10 - Prob. 10.2QECh. 10 - Prob. 10.3QECh. 10 - Prob. 10.4QECh. 10 - Prob. 10.5QECh. 10 - Prob. 10.6QECh. 10 - Prob. 10.7QECh. 10 - Prob. 10.8QECh. 10 - Prob. 10.9QECh. 10 - Prob. 10.10QE
Ch. 10 - Which atomic orbitals overlap to form the bonds in...Ch. 10 - Prob. 10.12QECh. 10 - Identify the hybrid orbitals used by boron in BCl3...Ch. 10 - Identify the hybrid orbitals used by antimony in...Ch. 10 - Prob. 10.15QECh. 10 - Prob. 10.16QECh. 10 - Prob. 10.17QECh. 10 - Prob. 10.18QECh. 10 - Prob. 10.19QECh. 10 - Prob. 10.20QECh. 10 - Compare and contrast the molecular orbital and...Ch. 10 - Describe the bonding in molecular orbital terms...Ch. 10 - Prob. 10.23QECh. 10 - Prob. 10.24QECh. 10 - Prob. 10.25QECh. 10 - Prob. 10.26QECh. 10 - Prob. 10.27QECh. 10 - Prob. 10.28QECh. 10 - Prob. 10.29QECh. 10 - Prob. 10.30QECh. 10 - Prob. 10.31QECh. 10 - Prob. 10.32QECh. 10 - Prob. 10.33QECh. 10 - Prob. 10.34QECh. 10 - Prob. 10.35QECh. 10 - Prob. 10.36QECh. 10 - Prob. 10.37QECh. 10 - Prob. 10.38QECh. 10 - Prob. 10.39QECh. 10 - Use the VSEPR model to predict the bond angles...Ch. 10 - Prob. 10.41QECh. 10 - Prob. 10.42QECh. 10 - For each of the following molecules, complete the...Ch. 10 - Prob. 10.44QECh. 10 - Prob. 10.45QECh. 10 - Prob. 10.46QECh. 10 - Indicate which molecules are polar and which are...Ch. 10 - Prob. 10.48QECh. 10 - Indicate which of the following molecules are...Ch. 10 - Prob. 10.50QECh. 10 - Prob. 10.51QECh. 10 - Prob. 10.52QECh. 10 - Prob. 10.53QECh. 10 - Prob. 10.54QECh. 10 - Prob. 10.55QECh. 10 - Prob. 10.56QECh. 10 - Prob. 10.57QECh. 10 - Prob. 10.58QECh. 10 - Prob. 10.59QECh. 10 - Prob. 10.60QECh. 10 - Prob. 10.61QECh. 10 - Prob. 10.62QECh. 10 - Prob. 10.63QECh. 10 - Prob. 10.64QECh. 10 - Prob. 10.65QECh. 10 - Prob. 10.66QECh. 10 - Prob. 10.67QECh. 10 - Prob. 10.68QECh. 10 - Prob. 10.69QECh. 10 - Prob. 10.70QECh. 10 - Prob. 10.71QECh. 10 - Prob. 10.72QECh. 10 - Identify the orbitals on each of the atoms that...Ch. 10 - Prob. 10.74QECh. 10 - Prob. 10.75QECh. 10 - How many sigma bonds and how many pi bonds are...Ch. 10 - Give the hybridization of each central atom in the...Ch. 10 - Prob. 10.78QECh. 10 - Prob. 10.79QECh. 10 - Prob. 10.80QECh. 10 - Prob. 10.81QECh. 10 - Predict the hybridization at each central atom in...Ch. 10 - Prob. 10.83QECh. 10 - Tetrafluoroethylene, C2F4, is used to produce...Ch. 10 - Prob. 10.85QECh. 10 - Prob. 10.86QECh. 10 - Prob. 10.87QECh. 10 - Prob. 10.88QECh. 10 - Prob. 10.89QECh. 10 - Prob. 10.90QECh. 10 - Prob. 10.91QECh. 10 - Prob. 10.92QECh. 10 - Prob. 10.93QECh. 10 - Prob. 10.94QECh. 10 - Prob. 10.95QECh. 10 - Prob. 10.96QECh. 10 - Prob. 10.97QECh. 10 - Prob. 10.98QECh. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - Prob. 10.102QECh. 10 - Prob. 10.103QECh. 10 - Prob. 10.104QECh. 10 - Prob. 10.105QECh. 10 - Following are the structures of three isomers of...Ch. 10 - The ions ClF2 and ClF2+ have both been observed....Ch. 10 - Aspirin, or acetylsalicylic acid, has the formula...Ch. 10 - Aspartame is a compound that is 200 times sweeter...Ch. 10 - Prob. 10.110QECh. 10 - Prob. 10.111QECh. 10 - Calcium cyanamide, CaNCN, is used both to kill...Ch. 10 - Histidine is an essential amino acid that the body...Ch. 10 - Formamide, HC(O)NH2, is prepared at high pressures...Ch. 10 - Prob. 10.115QECh. 10 - Prob. 10.116QECh. 10 - Prob. 10.117QECh. 10 - Prob. 10.118QECh. 10 - Prob. 10.119QECh. 10 - Prob. 10.120QECh. 10 - Prob. 10.121QECh. 10 - Prob. 10.122QECh. 10 - Prob. 10.123QECh. 10 - Prob. 10.124QECh. 10 - Two compounds have the formula S2F2. Disulfur...Ch. 10 - Prob. 10.126QECh. 10 - Prob. 10.127QE
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