Interpretation: The number of carbon atoms and
-bonds present in the following compound should be identified:
Concept Introduction: A method used to represent molecular structures of compounds is said to be bond line notation. In this notation, a line depicts a bond between two atoms and are drawn in a zigzag format. Atoms other than carbon and hydrogens are specifically depicted in this notation. It is assumed that carbon atoms are bonded to enough hydrogen atoms that are required to complete the octet.
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ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
- 3-25 Why are carbon and silicon reluctant to form ionic bonds?arrow_forwardDraw a Lewis structure for each of the following molecules: (a) chlorodifluoromethane, CHClF2 (b) propanoic acid, C2 H5CO2H (basic structure pictured below) (c) acetonitrile, CH3CH (the framework is H3C-C-N) (d) allene, H3CCCH2arrow_forwardAre the bonds in each of the following substances ionic,nonpolar covalent, or polar covalent? Arrange the substanceswith polar covalent bonds in order of increasing bond polarity:(a) KCl (b) P₄(c) BF₃(d) SO₂(e) Br₂(f) NOarrow_forward
- Draw a Lewis structure for each of the following molecules and ions. In each case, the atoms can be connected in only one way. (a) Br2 (b) H2S (c) N2H4 (d) N2H2 (e) CN- (f) NH4+ (g) N2 (h) O2arrow_forwardWhich two species have the same number of lone electron pairs in their Lewis structures?(a) H2O and H3O+(b) NH3 and H3O+(c) NH3 and CH4(d) NH3 and NH4+arrow_forwardDraw a Lewis Structure for each of the following species and assign formal charge where appropriate. Using electronegative values from the period table that was provided identify polar covalent bonds and label the atoms δ+ and δ−. For each of the molecules indicate whether or not it has a dipole moment. (a)CH5N (b) HCN (c) H2CO (d) CH3NC(e) CH3SOCH3 (f) H6BNarrow_forward
- Oxalic acid, H2C2O4, a poisonous colorless solid, is found in some vegetables such as spinach and rhubarb. It is present in concentrations well below the toxic limit, so you can't use this as a reason to refuse a helping of spinach. The order of atoms in a molecule of oxalic acid is HO2CCO2H. (a) How many unshared pairs of electrons are on each of the carbon atoms? (b) How many unshared pairs of electrons are on each of the oxygen atoms?arrow_forwardSemustine is a chemotherapy drug, and exerts it's anticancer activity by damaging the DNA of the cancer cells. Predict the approximate bond angle, (c) in Semustine and the molecular geometry of the indicated oxygen (a) and nitrogen (b) atoms. (a) NH (c) CH (b) Semustine NINAarrow_forwardFrom their positions in the periodic table, arrange the atoms in each of the following series in order of increasing electronegativity:(a) As, H, N, P, Sb(b) Cl, H, P, S, Si(c) Br, Cl, Ge, H, Sr(d) Ca, H, K, N, Si(e) Cl, Cs, Ge, H, Srarrow_forward
- Judging from their relative positions in the Periodic Table, which atom in each set is more electronegative? (a) Carbon or nitrogen (b) Chlorine or bromine (c) Oxygen or sulfurarrow_forwardUsing the bond energies as shown, determine the approximate enthalpy change for each of the following reactions:(a) Cl2(g) + 3F2(g) ⟶ 2ClF3(g)(b) H2 C = CH2(g) + H2(g) ⟶ H3 CCH3(g)(c) 2C2 H6(g) + 7O2(g) ⟶ 4CO2(g) + 6H2 O(g)arrow_forward2(a) Provide the Lewis structures for both CH3OH and C2H3Cl. 2(b) What is the largest bond angle among all the bond angles in CH3OH and C2H3Cl? Listthe three atoms making this largest bond angle, and estimate the value of the angle.2(c) What intermolecular forces are present(i) between CH3OH molecules?(ii) between C2H3Cl molecules?arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning