ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 1.3, Problem 5PTS
Interpretation Introduction

Interpretation: The Lewis structures of the small compounds have to be found by using their Lewis dot structures of involving atoms and by following the octet rule.

Concept introduction: The arrangement of atoms that are bonded together determines its constitution and molecular formula of that particular compound.  This concept is referred as structural isomers or in more modern term constitutional isomers.  Each atom has a typical valency or valence which is defined as the ability of an atom to form a chemical bond with other atoms.  For example, carbon has four valence or tetravalent that means carbon has the capacity to form four bonds with other elements or other atoms.  Nitrogen atom is trivalent.  Hydrogen is monovalent in nature.

Lewis dot structures are also called electron dot structures. The diagrams are named after Gilbert N. Lewis, who described them in his 1916 article entitled The Atom and the Molecule.  The number of electrons present in the outermost shell of an atom that participate in forming chemical bonds with other atoms is called valence electrons.  Each group present in the periodic table has specific common valence electrons.  Therefore, the position of the atom in the periodic table should be known for drawing the Lewis dot structures.

The Lewis structure of small compounds can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound.  In order to achieve complete noble gas configuration, octet rule is followed to find bonding nature of atoms.  Octet means 8 electrons in their valence shells.  The compounds which obey the octet rule are called stable compounds.

To find: The four constitutional isomers of C3H9N, their Lewis structures and the number of lone pair of electrons on the nitrogen atom in each isomer

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
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