
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Question
Chapter 1, Problem 65QP
Interpretation Introduction
Interpretation:
The amount of lead in grams contained in a given amount of blood is to be calculated.
Concept introduction:
Dimensional analysis is used to set up and solve a unit conversion problem using conversion factors. Dimensional analysis is a way to convert the units of measurement. In order to convert one unit to another, one needs to know the relationship between those units. These relationships are called conversion factors.
One part per million is the quantity that is equivalent to one milligram per liter of the solvent.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 1 Solutions
Chemistry
Ch. 1.1 - Practice Problem ATTEMPT
Express the freezing...Ch. 1.1 - Practice ProblemBUILD According to the website of...Ch. 1.1 - Prob. 1PPCCh. 1.2 - Prob. 1PPACh. 1.2 - Practice ProblemBUILD In Ray Bradbury's 1953 novel...Ch. 1.2 - Practice ProblemCONCEPTUALIZE If a single degree...Ch. 1.3 - Practice ProblemAttempt Given that 25 .0 mL of...Ch. 1.3 - Practice Problem BUILD
Calculate (a) the density...Ch. 1.3 - Practice ProblemCONCEPTUALIZE Using the picture of...Ch. 1.3 - The coldest temperature ever recorded on Earth was...
Ch. 1.3 - What is the density of an object that has a volume...Ch. 1.3 - A sample of water is heated from room temperature...Ch. 1.3 - Prob. 4CPCh. 1.4 - Prob. 1PPACh. 1.4 - Prob. 1PPBCh. 1.4 - Practice Problem CONCEPTUALIZE
The diagram on the...Ch. 1.4 - Prob. 1CPCh. 1.4 - Prob. 2CPCh. 1.5 - Practice Problem ATTEMPT
Determine the number of...Ch. 1.5 - Practice ProblemBUILD For each of the following...Ch. 1.5 - Prob. 1PPCCh. 1.5 - 1.5.1 What volume of water does the graduated...Ch. 1.5 - Which of the following is the sum of the following...Ch. 1.5 - The true dependence of y on x is represented by...Ch. 1.5 - What is the result of the following calculation to...Ch. 1.6 - Practice ProblemATTEMPT Perform the following...Ch. 1.6 - Practice ProblemBUILD Perform the following...Ch. 1.6 - Practice Problem CONCEPTUALIZE
A citrus dealer in...Ch. 1.6 - The density of lithium metal is 535 kg/m 3 . What...Ch. 1.6 - 1.6.2 Convert to liters.
Ch. 1.6 - 1.6.3 What is the volume of a 5.75-g object that...Ch. 1.6 - How many cubic centimeters are there in a cubic...Ch. 1.7 - Practice Problem ATTEMPT
An empty container with...Ch. 1.7 - Practice Problem BUILD
Another empty container...Ch. 1.7 - Practice ProblemCONCEPTUALIZE Several pieces of...Ch. 1.8 - Practice ProblemATTEMPT The American Heart...Ch. 1.8 - Practice ProblemBUILD An object has a mass of...Ch. 1.8 - Practice ProblemCONCEPTUALIZE The diagram contains...Ch. 1.9 - Practice ProblemATTEMPT The density of silver is...Ch. 1.9 - Practice ProblemBUILD The density of mercury is 13...Ch. 1.9 - Practice ProblemCONCEPTUALIZE Each diagram [ ( i )...Ch. 1 - 1.1
Given that the density of gold is , calculate...Ch. 1 - Prob. 2KSPCh. 1 - Determine the density of the following object in...Ch. 1 - A 28-kg child can consume a maximum of 23...Ch. 1 - Define the terms chemistry and matter.Ch. 1 - 1.2 Explain what is meant by the scientific...Ch. 1 - what is the difference between a hypothesis and a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Identify the elements present in the following...Ch. 1 - Identify the elements present in the following...Ch. 1 - Give an example for each of the following terms:...Ch. 1 - 1.9 Give an example of a homogeneous mixture and...Ch. 1 - Give an example of an element and a compound. How...Ch. 1 - What is the number of known elements?Ch. 1 - Give the names of the elements represented by the...Ch. 1 - 1.13 Give the chemical symbols for the following...Ch. 1 - Classify each of the following substances as an...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Identify each of the diagrams shown here as a...Ch. 1 - Identify each of the diagrams shown here as an...Ch. 1 - Name the SI base units that are important in...Ch. 1 - 1.19 Write the numbers represented by the...Ch. 1 - 1.20 What units do chemists normally use for the...Ch. 1 - 1.21 What is the difference between mass and...Ch. 1 - 1.22 Describe the three temperature scales used in...Ch. 1 - Bromine is a reddish-brown liquid. Calculate its...Ch. 1 - 1.24 The density of ethanol, a colorless liquid...Ch. 1 - Prob. 25QPCh. 1 - Prob. 26QPCh. 1 - 1.27 The density of water at is . What is the...Ch. 1 - The density of platinum (Pt) is 21 .5 g/cm 3 at...Ch. 1 - Convert the following temperatures to kelvin: (a)...Ch. 1 - Convert the following temperatures to degrees...Ch. 1 - 1.31 Which of the following illustrations best...Ch. 1 - The diagram shows balls of aluminum foil dropped...Ch. 1 - What is the difference between qualitative data...Ch. 1 - Using examples, explain the difference between a...Ch. 1 - How does an intensive property differ from an...Ch. 1 - Determine which of the following properties are...Ch. 1 - Classify the following as qualitative or...Ch. 1 - 1.38 Determine whether the following statements...Ch. 1 - Determine whether each of the following describes...Ch. 1 - 1.40 A student pours 44.3 g of water at into a...Ch. 1 - Prob. 41QPCh. 1 - Comment on whether each of the following...Ch. 1 - What is the advantage of using scientific notation...Ch. 1 - Define significant figure. Discuss the importance...Ch. 1 - Distinguish between the terms accuracy and...Ch. 1 - 1.46 Express the following numbers in scientific...Ch. 1 - Express the following as decimals: (a) 1.52 × 10 −...Ch. 1 - Express the answers to the following calculations...Ch. 1 - 1.49 Express the answers to the following...Ch. 1 - 1.50 Determine the number of significant figures...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 52QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Three students ( A, B, and C ) are asked to...Ch. 1 - Three apprentice tailors ( X, Y, and Z ) are...Ch. 1 - Carry out the following conversions: (a) 22.6 m to...Ch. 1 - Carry out the following conversions: (a) 242 lb to...Ch. 1 - The average speed of helium at 25°C is 1255 m/s ....Ch. 1 - Prob. 59QPCh. 1 - Prob. 60QPCh. 1 - Prob. 61QPCh. 1 - 1.62 A 6.0-ft person weighs 168 lb. Express this...Ch. 1 - The highest speed limit in the United States is 85...Ch. 1 - For a fighter jet to take off from the deck of an...Ch. 1 - Prob. 65QPCh. 1 - Prob. 66QPCh. 1 - Carry out the following conversions: (a) 185 nm to...Ch. 1 - 1.68 Aluminum is a lightweight metal used in...Ch. 1 - Prob. 69QPCh. 1 - (a) Carbon monoxide ( CO ) is a poisonous gas...Ch. 1 - Prob. 71QPCh. 1 - A human brain weighs about 1 kg and contains about...Ch. 1 - Using the appropriate number of significant...Ch. 1 - 1.74 A piece of metal with a mass of 13.2 g was...Ch. 1 - 1.75 Which of the following statements describe...Ch. 1 - 1.76 In determining the density of a rectangular...Ch. 1 - Calculate the mass of each of the following: (a) a...Ch. 1 - 1.78 A cylindrical glass tube 12.7 cm in length is...Ch. 1 - The following procedure was used to determine the...Ch. 1 - 1.80 The speed of sound in air at room temperature...Ch. 1 - A piece of silver ( Ag ) metal weighing 194.3 g is...Ch. 1 - The experiment described in Problem 1.81 is a...Ch. 1 - A lead sphere has a mass of 1 .20 × 10 4 g . and...Ch. 1 - Lithium is the least dense metal known ( density =...Ch. 1 - At what temperature does the numerical reading on...Ch. 1 - Prob. 86APCh. 1 - Prob. 87APCh. 1 - A sheet of aluminum ( A1 ) foil hat a total area...Ch. 1 - Prob. 89APCh. 1 - 1.90 The surface area and average depth of the...Ch. 1 - The unit "troy ounce" is often used for precious...Ch. 1 - Prob. 92APCh. 1 - Calculate the percent error for the following...Ch. 1 - In water conservation, chemists spread a thin film...Ch. 1 - 1.95 You are given a liquid. Briefly describe the...Ch. 1 - A gas company in Massachusetts charges $1 .30 for...Ch. 1 - Prob. 97APCh. 1 - 1.98 A bank teller is asked to assemble sets of...Ch. 1 - The men's world record for running a mile outdoors...Ch. 1 - 1.100 Venus, the second closest planet to the sun....Ch. 1 - Comment on whether each of the following is a...Ch. 1 - It has been estimated that 8.0 × 10 4 tons of gold...Ch. 1 - Prob. 103APCh. 1 - 1.104 Measurements show that 1.0 g of iron ...Ch. 1 - 1.105 The thin outer layer of Earth, called the...Ch. 1 - 1.106 The radius of a copper atom is roughly ....Ch. 1 - A graduated cylinder is filled to the 40.00-mL...Ch. 1 - A chemist mixes two liquids A and B to form a...Ch. 1 - A chemist in the nineteenth century prepared an...Ch. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 111APCh. 1 - Prob. 112APCh. 1 - Chalcopyrite, the principal one of copper ( Cu ) ,...Ch. 1 - 1.114 Vanillin (used to flavor vanilla ice cream...Ch. 1 - One gallon of gasoline in an automobile’s engine...Ch. 1 - 1.116 Magnesium (Mg) is a valuable metal used in...Ch. 1 - Prob. 117APCh. 1 - The natural abundances of elements in the human...Ch. 1 - A resting adult requires about 240 mL of pure...Ch. 1 - 1.120 (a) Referring to Problem 1.119. calculate...Ch. 1 - The medicinal thermometer commonly used in homes...Ch. 1 - TUMS is a popular remedy for acid indigestion. A...Ch. 1 - Prob. 123APCh. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...Ch. 1 - English writer and essayist Lady Mary Wortley...
Knowledge Booster
Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning

Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning


General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning