The answers to the given calculations are to be expressed with correct units and the correct number of significant figures. Concept introduction: Significant figures are the number of digits that are used to express a calculated quantity. It is very important to report a numerical result with the correct number of significant figures. The rules involved in determining the correct number of significant figures are: For addition and subtraction, the answer should contain same number of decimal places as present in the measurement with the least number of significant digits. In multiplication and division, the number of significant figures in the final product or quotient is determined by the original number that has the smallest number of significant figures. Exact numbers have an infinite number of significant figures. While reporting the final answer round up if the first non-significant digit is 5 or greater than 5 , and round down if it is below 5 .
The answers to the given calculations are to be expressed with correct units and the correct number of significant figures. Concept introduction: Significant figures are the number of digits that are used to express a calculated quantity. It is very important to report a numerical result with the correct number of significant figures. The rules involved in determining the correct number of significant figures are: For addition and subtraction, the answer should contain same number of decimal places as present in the measurement with the least number of significant digits. In multiplication and division, the number of significant figures in the final product or quotient is determined by the original number that has the smallest number of significant figures. Exact numbers have an infinite number of significant figures. While reporting the final answer round up if the first non-significant digit is 5 or greater than 5 , and round down if it is below 5 .
Solution Summary: The author explains that significant figures are the number of digits that are used to express a calculated quantity.
The answers to the given calculations are to be expressed with correct units and the correct number of significant figures.
Concept introduction:
Significant figures are the number of digits that are used to express a calculated quantity. It is very important to report a numerical result with the correct number of significant figures.
The rules involved in determining the correct number of significant figures are:
For addition and subtraction, the answer should contain same number of decimal places as present in the measurement with the least number of significant digits.
In multiplication and division, the number of significant figures in the final product or quotient is determined by the original number that has the smallest number of significant figures.
Exact numbers have an infinite number of significant figures.
While reporting the final answer round up if the first non-significant digit is 5 or greater than 5, and round down if it is below 5.
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)