Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
Question
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Chapter 1, Problem 25RPS

(a)

Interpretation Introduction

Interpretation: The correct number of significant figure for 1.52 and 9.44×103 has to be provided.

Concept Introduction:

Significant of zeroes:

  • Zeroes between two other significant digits are significant.
  • Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
  • Zeroes that are placeholders are not significant.

Rules used for significant figures in calculations:

Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.

Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.

Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.

(a)

Expert Solution
Check Mark

Answer to Problem 25RPS

9.44×103; The number of significant figures is three.

Explanation of Solution

In 1.52, the decimal numbers with no zeroes and has only the significant numbers.  So, the significant number is 3.

In 6.21×103, the decimal numbers with no zeroes and has only the significant numbers. So, the significant number is 3.

The multiplication of 1.52 and 9.44×103:

  × 1.52      significantfigure3(6.21×103)significantfigure3_=9.4392×103 _

The number of significant figures should the answer contain is the fewest number of significant figures of the given quantity.  Both the quantity possesses same significant figures.  Hence, the answer should be written as 9.44×103.  The significant figure is three.

(b)

Interpretation Introduction

Interpretation: The correct number of significant figure for 6.217×1035.23×102 has to be provided.

Concept Introduction:

Significant of zeroes:

  • Zeroes between two other significant digits are significant.
  • Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
  • Zeroes that are placeholders are not significant.

Rules used for significant figures in calculations:

Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.

Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.

Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.

(b)

Expert Solution
Check Mark

Answer to Problem 25RPS

5694; The number of significant figures is four.

Explanation of Solution

In 6.217×103, written as 6217 no decimal numbers; has only the significant numbers.  So, the significant number is 4.

In 5.23×102, written as 523 no decimal numbers and has only the significant numbers.  So, the significant number is 3.

The subtraction of 6217 and 523:

  -   6217 decimal places0523      decimal places 0_=5694    decimal places 0 _

The number of decimal places should the answer contain is the fewest decimal places of the given quantity.  Both the quantity possesses zero decimal places.  Hence, the answer should be written as 5694.  The significant figure is four.

(c)

Interpretation Introduction

Interpretation: The correct number of significant figure for 6.217×103÷5.23×102 has to be provided.

Concept Introduction:

Significant of zeroes:

  • Zeroes between two other significant digits are significant.
  • Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
  • Zeroes that are placeholders are not significant.

Rules used for significant figures in calculations:

Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.

Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.

Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.

(c)

Expert Solution
Check Mark

Answer to Problem 25RPS

11.9; The number of significant figures is three.

Explanation of Solution

In 6.217×103, writes as 6217 has no decimal numbers with no zeroes and has only the significant numbers.  So, the significant number is 4.

In 5.23×102, written as 523 has no decimal numbers with no zeroes and has only the significant numbers.  So, the significant number is 3.

The division of 6217 and 523:

  ÷ 6217  significantfigure4 523 significantfigure3_=11.887  _

The number of significant figures should the answer contain is the fewest number of significant figures of the given quantity.  Out of both the quantity 523 possesses 3 significant figures.  Hence, the answer should be written as 11.9 (rounding off).  The significant figure is three.

(d)

Interpretation Introduction

Interpretation: The correct number of significant figure for (0.0546)(16.0000)[7.77955.85]  has to be provided.

Concept Introduction:

Significant of zeroes:

  • Zeroes between two other significant digits are significant.
  • Zeroes to the right of a nonzero number, and also to the right of decimal place, are significant.
  • Zeroes that are placeholders are not significant.

Rules used for significant figures in calculations:

Rule 1: When adding or subtracting numbers, the number of decimal places in the answer is equal to the number of decimal places in the number with fewest digits after the decimal.

Rule 2: In multiplication or division, the number of significant figures in the answer is determined by the quantity with the fewest significant figures.

Rule 3: When a number is rounded off, the last digit to be retained is increased by one only if the following digit is 5 or greater.

(d)

Expert Solution
Check Mark

Answer to Problem 25RPS

0.122; The number of significant figures is three.

Explanation of Solution

The division and multiplication of:

  (0.0546)(16.0000)[7.77955.85] Multiplication of 0.0546 and 16.0000:_× 0.0546   significantfigure316.0000    significantfigure6_=0.874      significantfigure_Division of 7.779 and 55.85:_÷ 7.779    significantfigure4 55.85 significantfigure4_=0.1393 significantfigure_Finally,Mutiplication of 0.874 and 0.1393:_× 0.874   significantfigure30.1393   significantfigure4_=0.12174       _

Finally, on the multiplication of 0.874 and 0.1393 gives the value 0.12174.  Out of the two obtained quantity 0.874 possesses 3 significant figures.  Hence, the answer should be written as 0.122 (rounding off).  The significant figure is three.

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Chapter 1 Solutions

Chemistry & Chemical Reactivity

Ch. 1 - What is meant by the phrase sustainable...Ch. 1 - Prob. 4PSCh. 1 - Prob. 5PSCh. 1 - Prob. 6PSCh. 1 - Give the name of each of the following elements:...Ch. 1 - Give the name of each of the following elements:...Ch. 1 - Give the symbol for each of the following...Ch. 1 - Give the symbol for each of the following...Ch. 1 - In each of the following pairs, decide which is an...Ch. 1 - In each of the following pairs, decide which is an...Ch. 1 - An 18 g sample of water is decomposed into 2 g of...Ch. 1 - A sample of the compound magnesium oxide is...Ch. 1 - In each case, decide if the underlined property is...Ch. 1 - In each case, decide if the change is a chemical...Ch. 1 - Which part of the description of a compound or...Ch. 1 - Which part of the description of a compound or...Ch. 1 - The flashlight in the photo does not use...Ch. 1 - A solar panel is pictured in the photo. When light...Ch. 1 - Determine which of the following represent...Ch. 1 - Prob. 22PSCh. 1 - A hot metal block is plunged into water in a...Ch. 1 - A book is held at a height above the floor. It has...Ch. 1 - Prob. 25GQCh. 1 - Iron pyrite (fool's gold, page 11) has a shiny...Ch. 1 - Which observations below describe chemical...Ch. 1 - Which observations below describe chemical...Ch. 1 - The mineral fluorite contains the elements calcium...Ch. 1 - Azurite, a blue, crystalline mineral, is composed...Ch. 1 - You have a solution of NaCI dissolved in water....Ch. 1 - Small chips of iron are mixed with sand (see...Ch. 1 - Identify the following as either physical changes...Ch. 1 - Identify the following as either physical changes...Ch. 1 - In Figure 1.2 you see a piece of salt and a...Ch. 1 - In Figure 1.5 you see macroscopic and particulate...Ch. 1 - Prob. 37GQCh. 1 - The following photo shows copper balls, immersed...Ch. 1 - Categorize each of the following as an element, a...Ch. 1 - Categorize each of the following as an element, a...Ch. 1 - Make a drawing, based on the kinetic-molecular...Ch. 1 - Make a drawing, based on the kinetic-molecular...Ch. 1 - Hexane (C6H14, density = 0.766 g/cm3),...Ch. 1 - You have a sample of a white crystalline substance...Ch. 1 - You can figure out whether a solid floats or sinks...Ch. 1 - You are given a sample of a silvery metal. What...Ch. 1 - Milk in a glass bottle was placed in the freezing...Ch. 1 - Describe an experimental method that can be used...Ch. 1 - Diabetes can alter the density of urine, so urine...Ch. 1 - Prob. 50GQCh. 1 - The following photo shows the element potassium...Ch. 1 - Prob. 52GQCh. 1 - Four balloons are each filled with a different...Ch. 1 - Prob. 54GQCh. 1 - The photo below shows elemental iodine dissolving...Ch. 1 - A few years ago a young chemist in Vienna,...Ch. 1 - The distance between two carbon atoms in diamond...Ch. 1 - A student checked the accuracy of two standard...Ch. 1 - Prob. 3RCYUCh. 1 - The density of gold is 19,320 kg/m3. What is this...Ch. 1 - A particular paint has a density of 0.914 g/cm3....Ch. 1 - What is the fuel density in units of kg/L?Ch. 1 - What mass and what volume of fuel should have been...Ch. 1 - Confirm that a person swimming at the world record...Ch. 1 - At this world record rate, how long would it take...Ch. 1 - Prob. 2.3RACh. 1 - Many laboratories use 25C as a standard...Ch. 1 - The temperature on the surface of the Sun is 5.5 ...Ch. 1 - Prob. 3RPSCh. 1 - Make the following temperature conversions:Ch. 1 - A marathon distance race covers distance of 42.195...Ch. 1 - The average lead pencil, new and unused, is 19 cm...Ch. 1 - A standard U.S. postage stamp is 2.5 cm long and...Ch. 1 - A compact disc has a diameter of 11.8 cm. What is...Ch. 1 - A typical laboratory beaker has a volume of 250....Ch. 1 - Some soft drinks are sold in bottles with a volume...Ch. 1 - A book has a mass of 2.52 kg. What is this mass in...Ch. 1 - A new U.S. dime has a mass of 2.265 g. What is its...Ch. 1 - Ethylene glycol, C2H6O2, is an ingredient of...Ch. 1 - A piece of silver metal has a mass of 2.365 g. If...Ch. 1 - Prob. 15RPSCh. 1 - Which occupies a larger volume, 600 g of water...Ch. 1 - You are on a diet that calls for eating no more...Ch. 1 - A 2-in. piece of chocolate cake with frosting...Ch. 1 - Prob. 19RPSCh. 1 - Prob. 20RPSCh. 1 - You and your lab partner are asked to determine...Ch. 1 - The accepted value of the melting point of...Ch. 1 - Prob. 23RPSCh. 1 - Prob. 24RPSCh. 1 - Prob. 25RPSCh. 1 - Prob. 26RPSCh. 1 - To determine the average mass of a popcorn kernel,...Ch. 1 - Use the following graph to answer the following...Ch. 1 - Use the graph below to answer the following...Ch. 1 - Solve the following equation for the unknown...Ch. 1 - Solve the following equation for the unknown...Ch. 1 - Solve the following equation for the unknown...Ch. 1 - Prob. 34RPSCh. 1 - Molecular distances are usually given in...Ch. 1 - The separation between carbon atoms in diamond is...Ch. 1 - A red blood cell has a diameter of 7.5 m...Ch. 1 - The platinum-containing cancer drug cisplatin...Ch. 1 - Prob. 39RGQCh. 1 - You need a cube of aluminum with a mass of 7.6 g....Ch. 1 - You have a 250.0-mL graduated cylinder containing...Ch. 1 - Prob. 42RGQCh. 1 - The smallest repeating unit of a crystal of common...Ch. 1 - Diamond has a density of 3.513 g/cm3. The mass of...Ch. 1 - Prob. 45RGQCh. 1 - The density of pure water at various temperatures...Ch. 1 - Prob. 47RGQCh. 1 - The aluminum in a package containing 75 ft2 of...Ch. 1 - Fluoridation of city water supplies has been...Ch. 1 - About two centuries ago, Benjamin Franklin showed...Ch. 1 - Prob. 51RGQCh. 1 - A 26-meter-tall statue of Buddha in Tibet is...Ch. 1 - At 25 C, the density of water is 0.997 g/cm3,...Ch. 1 - Suppose your bedroom is 18 ft long and 15 ft wide,...Ch. 1 - A spherical steel ball has a mass of 3.475 g and a...Ch. 1 - You are asked to identify an unknown liquid that...Ch. 1 - You have an irregularly shaped piece of an unknown...Ch. 1 - There are five hydrocarbon compounds (compounds of...Ch. 1 - Suppose you have a cylindrical glass tube with a...Ch. 1 - Copper: Copper has a density of 8.96 g/cm3 An...Ch. 1 - Copper: (a) Suppose you have a cube of copper...Ch. 1 - You set out to determine the density of lead in...Ch. 1 - A sample of unknown metal is placed in a graduated...Ch. 1 - Iron pyrite is often called fool's gold because it...Ch. 1 - You can analyze for a copper compound in water...Ch. 1 - Prob. 67RIL
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