Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 1, Problem 1.70P
1-70 (Chemical Connections IA) The average lethal dose of heroin is 1.52 mg/kg of body weight. Estimate how many grams of heroin would be lethal for a 200-lb man.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 1 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 1.3 - Problem 1-1 Multiply: (a) (6.49107)(7.22103) (b)...Ch. 1.4 - Problem 1-2 Convert: (a) 64.0oC to Fahrenheit (b)...Ch. 1.5 - Prob. 1.3PCh. 1.5 - Problem 1-4 Convert the speed of sound, 332 m/s to...Ch. 1.5 - Problem 1-5 An intensive care patient is receiving...Ch. 1.7 - Problem 1-6 The density of titanium is 4.54 g/mL....Ch. 1.7 - Problem 1-7 An unknown substance has a mass of...Ch. 1.7 - Prob. 1.8PCh. 1.9 - Problem 1-9 How many calories are required to heat...Ch. 1.9 - Problem 1-10 A 100 g piece of iron at 25oC is...
Ch. 1.9 - Prob. 1.11PCh. 1 - 1-12 The life expectancy of a citizen in the...Ch. 1 - 1-13 Define the following terms: (a) Matter (b)...Ch. 1 - 1-14 In Table 1-4, you find four metals (iron,...Ch. 1 - 1-15 In a newspaper, you read that Dr. X claimed...Ch. 1 - Prob. 1.16PCh. 1 - 1-17 Write in exponential notation: (a) 0.351 (b)...Ch. 1 - 1-18 Write out in full: (a) 4.03 × l05 (b) 3.2 ×...Ch. 1 - 1-19 Multiply: (a) (2.16 × 105) (3.08 × 1012) (b)...Ch. 1 - Prob. 1.20PCh. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Prob. 1.24PCh. 1 - 1-25 How many significant figures are in the...Ch. 1 - 1-26 How many significant figures are in the...Ch. 1 - 1-27 Round off to two significant figures: (a)...Ch. 1 - 1-28 Multiply these numbers, using the correct...Ch. 1 - 1.29 Divide these numbers, using the correct...Ch. 1 - 1-30 Add these groups of measured numbers using...Ch. 1 - 1-31 In the SI system, the second is the base unit...Ch. 1 - 1-32 How many grams are in the following? (a)1 kg...Ch. 1 - 1-33 Estimate without actually calculating which...Ch. 1 - 1-34 For each of these, tell which figure is...Ch. 1 - 1-35 You are taken for a helicopter ride in Hawaii...Ch. 1 - Prob. 1.36PCh. 1 - Prob. 1.37PCh. 1 - 1-38 Make the following conversions (conversion...Ch. 1 - 1.39 Make the following metric conversions: (a)964...Ch. 1 - There are 2 bottles of cough syrup available on...Ch. 1 - 1-41 A humidifier located at a nursing station...Ch. 1 - 1-42 You drive in Canada where the distances are...Ch. 1 - 1-43 The speed limit in some European cities is 80...Ch. 1 - 1-44 Your car gets 25.00 miles on a gallon of gas....Ch. 1 - 145 Children’s Chewable Tylenol contains 80. mg of...Ch. 1 - 1-46 A patient weighs 186 lbs. She must receive an...Ch. 1 - 1-47 The doctor orders administration of a drug at...Ch. 1 - 1-48 The recommended pediatric dosage of Velosef...Ch. 1 - 1-49 A critical care physician prescribes an IV of...Ch. 1 - 1-50 If an IV is mixed so that each 150 mL...Ch. 1 - 1-51 A nurse practitioner orders isotonic sodium...Ch. 1 - 1-52 An order for a patient reads Give 40. mg of...Ch. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - 1-55 Does the chemical nature of a substance...Ch. 1 - 1-56 The volume of a rock weighing 1.075 kg is...Ch. 1 - 1-57 The density of manganese is 7.21 g/mL, that...Ch. 1 - 1.58 The density of titanium is 4.54 g/mL. What is...Ch. 1 - 1-59 An injection of 4 mg of Valium has been...Ch. 1 - 1-60 The density of methanol at 20oC is 0.791...Ch. 1 - 1-61 The density of dichloromethane, a liquid...Ch. 1 - 1-62 A sample of 10.00 g of oxygen has a volume of...Ch. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - 1-65 While you drive your car, your battery is...Ch. 1 - 1-66 How many calories are required to heat the...Ch. 1 - 1-67 If 168 g of an unknown liquid requires 2750...Ch. 1 - 1-68 The specific heat of steam is 0.48 cal/g oC....Ch. 1 - Prob. 1.69PCh. 1 - 1-70 (Chemical Connections IA) The average lethal...Ch. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - 1-73 (Chemical Connections 1C) Which would make a...Ch. 1 - Prob. 1.74PCh. 1 - 1-75 A brain weighing 1.0 lb occupies a volume of...Ch. 1 - 1-76 If the density of air is 1.25 10-3 g/cc,...Ch. 1 - 1-77 Classify these as kinetic or potential...Ch. 1 - 1-78 The kinetic energy possessed by an object...Ch. 1 - 1-79 A European car advertises an efficiency of 22...Ch. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - 1-82 When the astronauts walked on the Moon, they...Ch. 1 - 1-83 Which of the following is the largest mass...Ch. 1 - 1-84 Which quantity is bigger in each of the...Ch. 1 - 1-85 In Japan, high-speed “bullet trains” move...Ch. 1 - 1-86 The specific heats of some elements at 25oC...Ch. 1 - 1-87 Water that contains deuterium rather than...Ch. 1 - 1-88 One quart of milk costs 80 cents and one...Ch. 1 - 1-89 Consider butter, density 0.860 g/mL, and...Ch. 1 - 1-90 Which speed is the fastest? (a) 70 mi/h (b)...Ch. 1 - 1-91 In calculating the specific heat of a...Ch. 1 - 1-92 A solar cell generates 500. kJ of energy per...Ch. 1 - 1-93 The specific heat of urea is 1.339 J/g . If...Ch. 1 - Prob. 1.94PCh. 1 - 1-95 You receive an order for 60. mg of meperidine...Ch. 1 - Prob. 1.96PCh. 1 - Prob. 1.97PCh. 1 - 1-98 The antifreeze-coolant compound used in cars...Ch. 1 - Prob. 1.99PCh. 1 - Prob. 1.100PCh. 1 - Prob. 1.101PCh. 1 - Prob. 1.102PCh. 1 - Prob. 1.103PCh. 1 - Prob. 1.104PCh. 1 - Prob. 1.105PCh. 1 - Prob. 1.106PCh. 1 - Prob. 1.107PCh. 1 - Prob. 1.108PCh. 1 - Prob. 1.109PCh. 1 - Prob. 1.110PCh. 1 - 1-111 In the hospital, your doctor orders 100. mg...Ch. 1 - 1-112 A febrile, pediatric patient weighs 42...
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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